Scopus
YÖKSİS DOI Eşleşti
SJR Q1
Design and application of sporopollenin microcapsule supported palladium catalyst: Remarkably high turnover frequency and reusability in catalysis of biaryls
Journal of Colloid and Interface Science · Ocak 2017
YÖKSİS Kayıtları
Design and application of sporopollenin microcapsule supported palladium catalyst: Remarkably high turnover frequency and reusability in catalysis of biaryls
Journal of Colloid and Interface Science · 2017 SCI
Prof. Dr. İDRİS SARGIN →
YÖKSİS Kayıtları — ISSN Eşleşmesi
Effect of Au and Au Ag core shell nanoparticles on the SERS of bridging organic molecules
2010 ISSN: 00219797 SCI
Prof. Dr. BİLGE TANER →
Transport of Acids through Polyether Sulfone Anion Exchange Membrane
2001 ISSN: 00219797 SCI-Expanded 1 atıf
Prof. Dr. İLKAY HİLAL GÜBBÜK →
Synthesis characterization and sorption properties of silica gel immobilized Schiff base derivative
2008 ISSN: 00219797 SCI-Expanded 3 atıf
Prof. Dr. İLKAY HİLAL GÜBBÜK →
The sorption behavior of a nickel insolubilized humic acid system in a column arrangement
2005 ISSN: 0021-9797 SCI-Expanded
Prof. Dr. HÜSEYİN KARA →
Design and application of sporopollenin microcapsule supported palladium catalyst: Remarkably high turnover frequency and reusability in catalysis of biaryls
2017 ISSN: 00219797 SCI
Prof. Dr. İDRİS SARGIN →
Cobalt II and Nickel II Transfer through Charged Polysulfonated Cation Exchange Membranes
2000 ISSN: 00219797 SSCI
Prof. Dr. HÜSEYİN KARA →
Investigation of the properties of oil at the bleaching unit of an oil refinery
2004 ISSN: 0021-9797 SCI-Expanded
Prof. Dr. HÜSEYİN KARA →
Adsorption of Cu II Zn II Ni II Pb II and Cd II from aqueous solution on Amberlite IR 120 synthetic resin
2005 ISSN: 00219797 SSCI 179 atıf
Prof. Dr. GÜLŞİN ARSLAN →
Makale Bilgileri
ISSN00219797
Yayın TarihiOcak 2017
Cilt / Sayfa486 · 194-203
Scopus ID2-s2.0-84988966464
Özet
Bio-based catalyst support materials with high thermal and structural stability are desired for catalysts systems requiring harsh conditions. In this study, a thermally stable palladium catalyst (up to 440 °C) was designed from sporopollenin, which occurs naturally in the outer exine layer of pollens and is widely acknowledged as chemically very stable and inert biological material. Catalyst design procedure included (1) extraction of sporopollenin microcapsules from Betula pendula pollens (∼25 μm), (2) amino-functionalisation of the microcapsules, (3) Schiff base modification and (4) preparation of Pd(II) catalyst. The catalytic activity of the sporopollenin microcapsule supported palladium catalyst was tested in catalysis of biaryls by following a fast, simple and green microwave-assisted method. We recorded outstanding turnover number (TON: 40,000) and frequency (TOF: 400,000) for the catalyst in Suzuki coupling reactions. The catalyst proved to be reusable at least in eight cycles. The catalyst can be suggested for different catalyst systems due to its thermal and structural durability, reusability, inertness to air and its eco-friendly nature.
Yazarlar (5)
1
Talat Baran
2
Idris Sargin
ORCID: 0000-0003-3785-9575
3
Murat Kaya
4
Ayfer Menteş
5
Talip Ceter
Anahtar Kelimeler
Betula pendula
Pollen
Schiff base
Silylation
Suzuki coupling reaction
Kurumlar
Aksaray Üniversitesi
Aksaray Turkey
Kastamonu University
Kastamonu Turkey
Scimago Dergi (ISSN Eşleşmesi)
Journal of Colloid and Interface Science
Q1
OA
SJR Skoru1,642
H-Index297
YayıncıAcademic Press Inc.
ÜlkeUnited States
Biomaterials (Q1)
Colloid and Surface Chemistry (Q1)
Electronic, Optical and Magnetic Materials (Q1)
Surfaces, Coatings and Films (Q1)
Metrikler
68
Atıf
5
Yazar
5
Anahtar Kelime