Scopus
YÖKSİS DOI Eşleşti
SJR Q1
Production of magnetically recoverable, thermally stable, bio-based catalyst: Remarkable turnover frequency and reusability in Suzuki coupling reaction
Chemical Engineering Journal · Ocak 2018
YÖKSİS Kayıtları
Production of magnetically recoverable, thermally stable, bio-based catalyst: Remarkable turnover frequency and reusability in Suzuki coupling reaction
Chemical Engineering Journal · 2018 SCI
Prof. Dr. İDRİS SARGIN →
YÖKSİS Kayıtları — ISSN Eşleşmesi
Removal of Cr VI through calixarene based polymer inclusion membrane from chrome plating bath water
2016 ISSN: 13858947 SCI-Expanded
Prof. Dr. AYDAN YILMAZ →
Production of magnetically recoverable, thermally stable, bio-based catalyst: Remarkable turnover frequency and reusability in Suzuki coupling reaction
2018 ISSN: 1385-8947 SCI
Prof. Dr. İDRİS SARGIN →
Sponge-derived natural bioactive glass microspheres with self-assembled surface channel arrays opening into a hollow core for bone tissue and controlled drug release applications
2021 ISSN: 1385-8947 SCI-Expanded Q1
Prof. Dr. İDRİS SARGIN →
Electron-enriched regulation of sulfur-active site for accelerating atomic hydrogen desorption of S-rich MoWS2+x cocatalyst toward efficient photocatalytic H2 evolution of TiO2
2022 ISSN: 1385-8947 SCI-Expanded Q1
Prof. Dr. İMREN HATAY PATIR →
Fast, visual, and quantitative monitoring of N2H4 by two ratiometric fluorescent probes in environmental media and biological systems
2023 ISSN: 1385-8947 SCI-Expanded Q1
Prof. Dr. SERKAN ERDEMİR →
Fast, visual, and quantitative monitoring of N2H4 by two ratiometric fluorescent probes in environmental media and biological systems
2023 ISSN: 1385-8947 SCI-Expanded Q1
Doç. Dr. MEHMET OĞUZ →
Makale Bilgileri
ISSN13858947
Yayın TarihiOcak 2018
Cilt / Sayfa331 · 102-113
Scopus ID2-s2.0-85037690619
Özet
In any catalysis system, regeneration of the used catalyst is of great importance to reduce the cost of industrial applications. However, recovery of the used catalyst from the reaction medium is a difficult task and this can hinder regeneration process. Magnetic separation has emerged as an effective tool to overcome the recovery problem. Hence, in this study a magnetically recoverable sporopollenin-based Pd catalyst has been designed and used in synthesis of biaryl compounds via Suzuki coupling reaction. The thermally stable catalyst exhibited excellent catalytic behaviour without giving any by-products. It is noteworthy that despite their low product yield of aryl chlorides in coupling reactions, remarkable product yields which are comparable to those of aryl bromides and iodides were recorded for aryl chlorides. With very low catalyst loading (1 × 10−3 mol%), the catalyst gave TOFs values exceeding one million; i.e., 1.237.500 in very short reaction time. Due to its magnetically separable nature, the catalyst could be recovered from the reaction media easily by increasing the reusability of the catalyst. Even in tenth run biphenyl yield dropped from 99 to 93%.
Yazarlar (6)
1
Talat Baran
2
Idris Sargin
ORCID: 0000-0003-3785-9575
3
Murat Kaya
4
Povilas Mulerčikas
5
Sonata Kazlauskaitė
6
Ayfer Menteş
Anahtar Kelimeler
Biaryl
Juglans cinerea
Magnetite
Pollen
Schiff base
Kurumlar
Aksaray Üniversitesi
Aksaray Turkey
Vytautas Magnus University
Kaunas Lithuania
Scimago Dergi (ISSN Eşleşmesi)
Chemical Engineering Journal
Q1
SJR Skoru2,259
H-Index369
YayıncıElsevier B.V.
ÜlkeNetherlands
Chemical Engineering (miscellaneous) (Q1)
Chemistry (miscellaneous) (Q1)
Environmental Chemistry (Q1)
Industrial and Manufacturing Engineering (Q1)
Metrikler
56
Atıf
6
Yazar
5
Anahtar Kelime