Scopus
YÖKSİS Eşleşti
Voltammetric determination of facilitated ion transfer across the water/1,2-dichloroethane interface
Russian Journal of Electrochemistry · Şubat 2014
YÖKSİS Kayıtları
Voltammetric determination of facilitated ion transfer across the water/1,2-dichloroethane interface
Russian Journal of Electrochemistry · 2014 SCI-Expanded
DOÇENT CANAN BAŞLAK →
Makale Bilgileri
DergiRussian Journal of Electrochemistry
Yayın TarihiŞubat 2014
Cilt / Sayfa50 · 180-185
Scopus ID2-s2.0-84896814006
Özet
The facilitated transfer characteristics of Cd2+ ion by 4-morpholinoacetophenone-4-ethyl-3-thiosemicarbazone (MAPET) across water/1,2-dicholoroethane (1,2-DCE) interface and its electrochemical properties were investigated by voltammetric measurements. Cyclic voltammetry (CV) was employed to examine the transfer in the conditions of the ligand (organic phase) in excess and the obtained transfer peaks have reversible nature at different metal concentrations and scan rates. The dependence of the obtained half-wave transfer potential on MAPET concentration showed that the equilibrium is effectively displaced towards a 1: 3 (Cd2+: ligand) stoichiometry with an association constant of logβ 30 = 12.96 ± 0.09 for the Cd2+ ion, corresponding to the TIC/TID mechanism. © 2014 Pleiades Publishing, Ltd.
Yazarlar (2)
1
Canan Baslak
2
Tevfik Atalay
Anahtar Kelimeler
Cd ion 2+
cyclic voltammetry
facilitated ion transfer
ITIES
thiosemicarbazone
Kurumlar
Necmettin Erbakan Üniversitesi
Meram Turkey
Selçuk Üniversitesi
Selçuklu Turkey
Metrikler
2
Atıf
2
Yazar
5
Anahtar Kelime