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Upper rim-functionalized calix[4]arene-based l-proline as organocatalyst for direct asymmetric aldol reactions in water and organic media

Tetrahedron · Aralık 2014

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YÖKSİS Kayıtları
Upper rim functionalized calix 4 arene based l proline as organocatalyst for direct asymmetric aldol reactions in water and organic media
Tetrahedron · 2014 SCI-Expanded 3 atıf
DOÇENT ARZU UYANIK →
Upper rim functionalized calix 4 arene based l proline as organocatalyst for direct asymmetric aldol reactions in water and organic media
Tetrahedron · 2014 SCI
PROFESÖR MUSTAFA YILMAZ →

Makale Bilgileri

DergiTetrahedron
Yayın TarihiAralık 2014
Cilt / Sayfa70 · 9307-9313
Özet The synthesis of upper rim-functionalized calix[4]arene-based l-proline was described, and its catalytic efficiency as organocatalyst for the enantioselective aldol reaction in water was investigated. The results showed that the nature of the hydrophobic cavity of calixarene is critical for catalytic activity in water. The products of the reaction between various ketones and aldehydes with anti-configuration were obtained in high yields (up to 94%) with high diastereo- (up to 95:5 dr) and enantioselectivities (up to 80% ee).

Yazarlar (4)

1
Arzu Uyanik
2
Mevlut Bayrakci
3
S. Eymur
ORCID: 0000-0003-3346-6010
4
Mustafa Yilmaz

Kurumlar

Giresun Üniversitesi
Giresun Turkey
Niğde Ömer Halisdemir University
Nigde Turkey
Selçuk Üniversitesi
Selçuklu Turkey

Metrikler

26
Atıf
4
Yazar

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