Scopus
YÖKSİS DOI Eşleşti
SJR Q1
Preparation of One-Pot Immobilized Lipase with Fe3O4 Nanoparticles Into Metal-Organic Framework For Enantioselective Hydrolysis of (R,S)-Naproxen Methyl Ester
Chemcatchem · Ağustos 2021
YÖKSİS Kayıtları
Preparation of One\u2010Pot Immobilized Lipase with Fe\n 3\n O\n 4\n Nanoparticles Into Metal\u2010Organic Framework For Enantioselective Hydrolysis of (\n R,S\n )\u2010Naproxen Methyl Ester
ChemCatChem · 2021 SCI-Expanded
Prof. Dr. ELİF ÖZYILMAZ →
Preparation of One-Pot Immobilized Lipase with Fe3O4 Nanoparticles Into Metal-Organic Framework For Enantioselective Hydrolysis of (R,S)-Naproxen Methyl Ester
ChemCatChem · 2021 SCI-Expanded
Prof. Dr. MUSTAFA YILMAZ →
YÖKSİS Kayıtları — ISSN Eşleşmesi
Catalytic Hydrogen Evolution by Tungsten Disulfide at Liquid Liquid Interfaces
2014 ISSN: 18673880 SCI-Expanded
Prof. Dr. İMREN HATAY PATIR →
Enhanced Hydrogen Evolution Catalysis Based on Cu Nanoparticles Deposited on Carbon Nanotubes at the Liquid Liquid Interface
2016 ISSN: 18673880 SCI-Expanded
Prof. Dr. İMREN HATAY PATIR →
Catalytic Hydrogen Evolution by Tungsten Disulfide at Liquid-Liquid Interfaces
2014 ISSN: 1867-3880 SCI
Doç. Dr. EMRE ASLAN →
Enhanced Hydrogen Evolution Catalysis Based on Cu Nanoparticles Deposited on Carbon Nanotubes at the Liquid/Liquid Interface
2016 ISSN: 1867-3880 SCI
Doç. Dr. EMRE ASLAN →
Preparation of One-Pot Immobilized Lipase with Fe3O4 Nanoparticles Into Metal-Organic Framework For Enantioselective Hydrolysis of (R,S)-Naproxen Methyl Ester
2021 ISSN: 1867-3880 SCI-Expanded Q2
Prof. Dr. MUSTAFA YILMAZ →
Enhanced Photocatalytic Hydrogen Evolution and Antibacterial Activities of Ternary Chevrel Phases
2023 ISSN: 1867-3880 SCI-Expanded Q2
Doç. Dr. EMRE ASLAN →
Enhanced Photocatalytic Hydrogen Evolution and Antibacterial Activities of Ternary Chevrel Phases
2023 ISSN: 1867-3880 SCI-Expanded Q1
Arş. Gör. İLKNUR AKSOY ÇEKCEOĞLU →
Enhanced Photocatalytic Hydrogen Evolution and Antibacterial Activities of Ternary Chevrel Phases
2023 ISSN: 1867-3880 SCI-Expanded Q2
Prof. Dr. İMREN HATAY PATIR →
Makale Bilgileri
Dergi
Chemcatchem
ISSN18673880
Yayın TarihiAğustos 2021
Cilt / Sayfa13 · 3687-3694
Scopus ID2-s2.0-85108297384
Özet
Immobilization of enzyme to magnetic metal-organic frameworks (MOF) can preserve biological functionality in harsh environments to increase enzymes activity, stability, and improve reusability. The magnetic Fe3O4 nanoparticles were treated with calix[4]arene tetracarboxylic acid (Calix) and Candida rugosa lipase (CRL), and then encapsulated into the zeolitic imidazole framework-8 (Fe3O4@Calix-ZIF-8@CRL). The lipase activity data of Fe3O4@Calix-ZIF-8@CRL was 2.88 times higher than that of the Fe3O4@ZIF-8@CRL (without Calix). The catalytic properties of immobilized lipases were studied on the enantioselective hydrolysis of R/S-naproxen methyl ester. It was also observed that Fe3O4@Calix-ZIF-8@CRL has excellent enantioselectivity (E=371) compared to Fe3O4@ZIF-8@CRL (E=131). Furthermore, Fe3O4@Calix-ZIF-8@CRL was seen to still retain 30 % of the conversion rate after the fifth reuse. This work may also be useful for the pharmaceutical industry due to the increased reusability and stability of enzymes, the enantiomeric selectivity exhibited by MOF-enzyme biocomposites, and the significant differences in the biological activities of the enantiomers.
Yazarlar (3)
1
Elif Ozyilmaz
2
Sebahat Ascioglu
3
Mustafa Yilmaz
Anahtar Kelimeler
biocatalysis
enantioselectivity
lipase
magnetic nanoparticles
metal organic frameworks
Kurumlar
Selçuk Üniversitesi
Selçuklu Turkey
Scimago Dergi (ISSN Eşleşmesi)
ChemCatChem
Q1
SJR Skoru0,900
H-Index144
YayıncıWiley - VCH Verlag GmbH & CO. KGaA
ÜlkeGermany
Inorganic Chemistry (Q1)
Organic Chemistry (Q1)
Physical and Theoretical Chemistry (Q1)
Catalysis (Q2)
Metrikler
26
Atıf
3
Yazar
5
Anahtar Kelime