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Synthesis, characterization, thermal, and redox properties of a vic-dioxime and its metal complexes

Journal of Coordination Chemistry · Eylül 2010

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YÖKSİS Kayıtları
Synthesis characterization thermal and redox properties of a vic dioxime and its metal complexes
Journal of Coordination Chemistry · 2010 SCI 6 atıf
PROFESÖR PERVİN SOYLU →
Synthesis characterization thermal and redox properties of a vic dioxime and its metal complexes
Journal of Coordination Chemistry · 2010 SCI
PROFESÖR BİLGE TANER →

Makale Bilgileri

DergiJournal of Coordination Chemistry
Yayın TarihiEylül 2010
Cilt / Sayfa63 · 3083-3092
Özet A new vic-dioxime ligand containing benzophenone hydrazone units, N'-(benzophenone hydrazone)glyoxime [LH2] has been prepared from benzophenone hydrazone and anti-chloroglyoxime in absolute ethanol. Mononuclear nickel(II), cobalt(II), copper(II), zinc(II), and cadmium(II) complexes were also synthesized. Ligand and complexes were characterized by elemental analyses, FT-IR, 1H NMR, and 13C NMR spectroscopy, magnetic moments, and DTA/TG techniques. On the basis of the magnetic and spectral evidences a square-planar geometry for Ni(II) and Cu(II) complexes, tetrahedral for Cd(II) and Zn(II) complexes, and octahedral for Co(II) complex were proposed. Redox behaviors of ligand and its complexes were also investigated by cyclic voltammetry at the glassy carbon electrode. © 2010 Taylor & Francis.

Yazarlar (7)

1
Asuman Ucar
2
P. Deveci
3
B. Taner
4
Mukerrem Findik
5
Soner Bereket
6
E. Özcan
7
Ali Osman Solak

Anahtar Kelimeler

Benzophenone hydrazone Cyclic voltammetry DTA/TG techniques Transition metal complexes vic-Dioxime

Kurumlar

Ankara Üniversitesi
Ankara Turkey
Selçuk Üniversitesi
Selçuklu Turkey

Metrikler

9
Atıf
7
Yazar
5
Anahtar Kelime

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