Scopus
YÖKSİS Eşleşti
The first example of calix[4]pyrrole functionalized vic-dioxime ligand: Synthesis, characterization, spectroscopic studies and redox properties of the mononuclear transition metal complexes
Inorganica Chimica Acta · Kasım 2010
YÖKSİS Kayıtları
The first example of calix 4 pyrrole functionalized vic dioxime ligand Synthesis characterization spectroscopic studies and redox properties of the mononuclear transition metal complexes
Inorganica Chimica Acta · 2010 SCI 13 atıf
PROFESÖR PERVİN SOYLU →
The first example of calix 4 pyrrole functionalized vic dioxime ligand Synthesis characterization spectroscopic studies and redox properties of the mononuclear transition metal complexes
Inorganica Chimica Acta · 2010 SSCI 2 atıf
PROFESÖR BİLGE TANER →
Makale Bilgileri
DergiInorganica Chimica Acta
Yayın TarihiKasım 2010
Cilt / Sayfa363 · 4017-4023
Scopus ID2-s2.0-77957975153
Özet
Novel calix[4]pyrrole bearing vic-dioxime ligand (LH2) of the general formula, R1R2C2N2O 2H2 (where, R1 = C6H5- and R2 = C39H50N5-) has been synthesized by the reaction of anti-chlorophenylglyoxime with 3-aminophenylcalix[4]pyrrole at room temperature. The mononuclear Cu(II), Ni(II) and Co(II)complexes of this vic-dioxime ligand were prepared and their structures were confirmed by elemental analysis, FT-IR, TGA and magnetic susceptibility measurements; the HMBC, DEPT, 1H and 13C NMR spectra of the LH2 ligand were also reported. The electrochemical property of the complexes was investigated in DMSO by cyclic voltammetry at 200 mV s-1 scan rate. The cyclic voltammetric measurements clearly indicated that Co(LH)2·2H2O complex differs from the Ni(LH)2 and Cu(LH)2 complexes upon the exhibition of quasi-reversible one-electron transfer reduction process in the negative region instead of an irreversible process. © 2010 Elsevier B.V. All rights reserved.
Yazarlar (5)
1
B. Taner
2
P. Deveci
3
Soner Bereket
4
Ali Osman Solak
5
E. Özcan
Anahtar Kelimeler
3-Aminophenylcalix[4]pyrrole
Calix[4]pyrrole
Cyclic voltammetry
Transition metal complexes
vic-Dioximes
Kurumlar
Ankara Üniversitesi
Ankara Turkey
Selçuk Üniversitesi
Selçuklu Turkey
Metrikler
19
Atıf
5
Yazar
5
Anahtar Kelime