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Synthesis of a new colorimetric receptor based on calix[4]pyrrole binding oxime for selective recognition of fluoride ions

Supramolecular Chemistry · Şubat 2014

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YÖKSİS Kayıtları
Synthesis of a new colorimetric receptor based on calix 4 pyrrole binding oxime for selective recognition of fluoride ions
Supramolecular Chemistry · 2013 SCI 5 atıf
PROFESÖR PERVİN SOYLU →
Synthesis of a new colorimetric receptor based on calix 4 pyrrole binding oxime for selective recognition of fluoride ions
Supramolecular Chemistry · 2014 SCI-Expanded 5 atıf
PROFESÖR ÖNDER ALICI →
Synthesis of a new colorimetric receptor based on calix 4 pyrrole binding oxime for selective recognition of fluoride ions
Supramolecular Chemistry · 2013 SSCI 4 atıf
PROFESÖR BİLGE TANER →

Makale Bilgileri

DergiSupramolecular Chemistry
Yayın TarihiŞubat 2014
Cilt / Sayfa26 · 119-124
Özet A colorimetric anion sensor -meso-heptaethylcalix[4]pyrrole-meso-3- aminophenyl-p-nitrobenzaldoxime was synthesised and characterised by various spectroscopic techniques. Anion-binding studies were carried out using UV-vis, and 1H NMR titrations, revealing that the receptor exhibits selective recognition towards F- over other anions. The selectivity for F - among the halides is attributed mainly to the hydrogen bond interaction of the receptor with F-. Receptor showed colour change from colourless to yellow in the presence of tetrabutylammonium fluoride with 1:2 stoichiometry. Cyclic voltammetry studies, carried out in CH3CN, provided evidence of an anion-dependent electrochemical response with F- ion. This response was particularly dramatic in the case of receptor after the addition of ∼1 equiv. of FO ion. © 2013 Taylor and Francis.

Yazarlar (3)

1
B. Taner
2
Onder Alici
ORCID: 0000-0001-5982-5128
3
P. Deveci

Anahtar Kelimeler

anion recognition calix[4]pyrrole-based receptor cyclic voltammetry oxime

Kurumlar

Selçuk Üniversitesi
Selçuklu Turkey

Metrikler

11
Atıf
3
Yazar
4
Anahtar Kelime

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