Scopus
YÖKSİS Eşleşti
New supramolecular compounds: The complexes of nickel(II), copper(II), cobalt(II), cadmium(II) and zinc(II) with anti- [N-(4-aminophenyl)aza-15-crown-5]-4-(phenoxy)phenylglyoxime ligand
Journal of Inclusion Phenomena and Macrocyclic Chemistry · Ağustos 2015
YÖKSİS Kayıtları
New supramolecular compounds the complexes of nickel II copper II cobalt II cadmium II and zinc II with anti N 4 aminophenyl aza 15 crown 5 4 phenoxy phenylglyoxime ligand
Journal of Inclusion Phenomena and Macrocyclic Chemistry · 2015 SCI
PROFESÖR PERVİN SOYLU →
New supramolecular compounds the complexes of nickel II copper II cobalt II cadmium II and zinc II with anti N 4 aminophenyl aza 15 crown 5 4 phenoxy phenylglyoxime ligand
Journal of Inclusion Phenomena and Macrocyclic Chemistry · 2015 SSCI
PROFESÖR BİLGE TANER →
Makale Bilgileri
DergiJournal of Inclusion Phenomena and Macrocyclic Chemistry
Yayın TarihiAğustos 2015
Cilt / Sayfa82 · 407-415
Scopus ID2-s2.0-84943399030
Özet
A new vic-dioxime ligand (1), bearing pendant an azacrown ether moiety and its soluble mononuclear cadmium(II), zinc(II), nickel(II), copper(II) and cobalt(II) complexes were obtained with the metal: ligand ratios of 1:2 and 1:1. The structures of the ligand and its complexes were verified using Fourier transform infrared (FT-IR), ultraviolet-visible (UV-Vis), mass spectrometry (MS), 1H and 13C NMR techniques. More detailed information about the structure of the 1 was provided by the two-dimensional (2D) heteronuclear single quantum coherence and heteronuclear multiple bond correlation techniques. The complexation properties of the ligand 1 were studied in the presence of different cations such as Pb2+, Zn2+,Cu2+, Cr3+, Hg2+, Zn2+, Fe3+ and Al3+ by UV-Vis spectroscopy and 1H NMR titration methods. All experimental results indicated that the new ligand acts as a selective compound only for Hg+2 cation. The redox behaviour of the complexes, were investigated by cyclic voltammetry at the glassy carbon electrode in 0.1 M tetrabutylamoniumtetrafluoroborate in dimethyl sulfoxide.
Yazarlar (8)
1
Kürşat Özpinar
2
P. Deveci
3
Merve Kilinç
4
E. Özcan
5
Burcu Dilyüz Karaman
6
Havva Karaarslan
7
B. Taner
8
Z. Kılıç
Anahtar Kelimeler
Azacrown ether
Metal complex
Redox property
Solid and solution state studies
Kurumlar
Ankara Üniversitesi
Ankara Turkey
Selçuk Üniversitesi
Selçuklu Turkey
Metrikler
4
Atıf
8
Yazar
4
Anahtar Kelime