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Comparative study of influences of gamma rays on calix[4]arene and 25,27-di(4-nitrobenzyl)-26,28-dihydroxycalix[4]arene: EPR study

Acta Physica Polonica A · Eylül 2017

Makale Bilgileri

DergiActa Physica Polonica A
Yayın TarihiEylül 2017
Cilt / Sayfa132 · 1211-1213
Erişim🔓 Açık Erişim
Özet In the present study, calix[4]arene and its derivate 25,27-di(4-nitrobenzyl)-26,28-dihydroxycalix[4]arene were irradiated for 72 hours by 60Co gamma rays at dose rate of 0.720 kGy/h. These irradiated samples were analyzed by EPR method and it was found that one type of radical was produced in calix [4] arene, and two type of radicals were produced in 25,27-di(4-nitrobenzyl)-26,28-dihydroxycalix [4] arene. The measurements were performed in the temperature range of 273-400 K using x-band EPR spectrometer. It was observed that the spectra, obtained from two samples, have very weak temperature dependence. Hyperfine and g parameters were calculated for two samples.

Yazarlar (5)

1
Y. Ceylan
2
Keziban Usta
3
N. Ceylan
4
Ayhan Usta
5
Y. Koc

Kurumlar

Selçuk Üniversitesi
Selçuklu Turkey