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Organometallic chiral Schiff base for enantio-selective fluorescent recognition of methionine

Chemical Papers · Ekim 2017

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YÖKSİS Kayıtları
Organometallic chiral Schiff base for enantio-selective fluorescent recognition of methionine
Chemical Papers · 2017 SCI-Expanded
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Makale Bilgileri

DergiChemical Papers
Yayın TarihiEkim 2017
Cilt / Sayfa71 · 1855-1862
Özet Herein, the synthesis and characterization of a novel chiral Schiff bases derived from ferrocene, coded as 3, have been reported. The sensing behavior of the synthesized compound has been examined towards the enantiomers of some amino acids (methionine, alanine, serine, histidine, and threonine) by spectrofluorimetric method. The fluorescence response of compound 3 showed noticeable enhancement upon addition of d-methionine compared to l-methionine and kept nearly linear correlation with the concentration of d-methionine. The value of enantiomeric fluorescence difference ratio (ef) has been determined to be 1.54 when d - and l- methionine amount is 100 times more than compound 3. The results showed that the compound 3 can be used as a sensor for enantio-selective recognition of d-methionine.

Yazarlar (5)

1
Asuman Ucar
2
Mukerrem Findik
3
Haluk Bingol
4
Ersin Guler
5
E. Özcan

Anahtar Kelimeler

Amino acid methylester Chiral sensor Ferrocene Fluorescence sensor Molecular recognition Schiff base

Kurumlar

Aǧrı İbrahim Çeçen Üniversitesi
Agri Turkey
Necmettin Erbakan Üniversitesi
Meram Turkey
Selçuk Üniversitesi
Selçuklu Turkey

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15
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5
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6
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