Scopus
YÖKSİS Eşleşti
Kinetics of the copolymerization of alkylene oxides with glycidyl methacrylate
Journal of Applied Polymer Science · Aralık 2007
YÖKSİS Kayıtları
Kinetics of the copolymerization of alkylene oxides with glycidyl methacrylate
Journal of Applied Polymer Science · 2007 SSCI
PROFESÖR ZAFER YAZICIGİL →
Kinetics of the copolymerization of alkylene oxides with glycidyl methacrylate
Journal of Applied Polymer Science · 2007 SCI-Expanded
PROFESÖR AHMET KOÇAK →
Makale Bilgileri
DergiJournal of Applied Polymer Science
Yayın TarihiAralık 2007
Cilt / Sayfa106 · 3710-3715
Scopus ID2-s2.0-36348999127
Özet
In the present study, the kinetics of copolymerization reaction of propylene oxide (PO) and butylene oxide (BO) with glycidyl methacrylate (GMA) in the presence of BF3 · O(C2H5) 2 catalyst were investigated. The kinetic parameters and activation energy of the copolymerization reaction were calculated. The amounts of reacting PO, BO, and GMA during copolymerization were determined by chromatographic method, because the same copolymerization conditions were carried out for them. It was determined that the copolymerization rate of PO (r0) and BO (r0) was higher than that of GMA, but activation energy (E) of GMA was higher than that of PO and BO. The rate of reaction, the rate constant, and activation energy were calculated from the amount of copolymer obtained with respect to time. The structures of synthesized copolymers were determined by the spectral and chemical analysis methods. © 2007 Wiley Periodicals, Inc.
Yazarlar (3)
1
Gulnare Ahmetli
2
Ahmet Kocak
3
Zafer Yazicigil
Anahtar Kelimeler
Alkylene oxides
Copolymerization
Glycidyl methacrylate
Kinetics (polymer)
Kurumlar
Selçuk Üniversitesi
Selçuklu Turkey
Metrikler
3
Atıf
3
Yazar
4
Anahtar Kelime