Scopus
YÖKSİS DOI Eşleşti
SJR Q2
Synthesis, spectroscopic studies and nonlinear optical behavior of N,N′-bis(2-hydroxy-1-naphthylmethylidene)-1-methyl-1,2-diaminoethane-N,N′,O,O′-nickel(II)
Journal of Molecular Structure · Aralık 2006
YÖKSİS Kayıtları
Synthesis spectroscopic studies and nonlinear optical behavior of N N bis 2 hydroxy 1 naphthylmethylidene 1 methyl 1 2 diaminoethane N N O O nickel II
Journal of Molecular Structure · 2006 SCI-Expanded 14 atıf
Prof. Dr. ASLI KARAKAŞ →
YÖKSİS Kayıtları — ISSN Eşleşmesi
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Nonlinear optical properties spectroscopic studies and structure of 2 hydroxy 3 methoxy N 2 chloro benzyl benzaldehyde imine
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Synthesis spectroscopic studies and nonlinear optical behavior of N N bis 2 hydroxy 1 naphthylmethylidene 1 methyl 1 2 diaminoethane N N O O nickel II
2006 ISSN: 00222860 SCI-Expanded 14 atıf
Prof. Dr. ASLI KARAKAŞ →
Makale Bilgileri
ISSN00222860
Yayın TarihiAralık 2006
Cilt / Sayfa800 · 18-22
Scopus ID2-s2.0-33750706870
Özet
A Schiff base complex N,N′-bis(2-hydroxy-1-naphthylmethylidene)-1-methyl-1,2- diaminoethane-N,N′,O,O′-nickel(II) has been synthesized. The title compound has been characterized by FT-IR and UV-vis spectroscopies. The UV-vis experiments indicate that the compound has solvatochromism in the UV region, implying non-zero molecular first hyperpolarizability. To investigate microscopic second-order nonlinear optical (NLO) behavior of the examined complex, the electric dipole moments (μ) and the first static hyperpolarizabilities (β) were computed using Finite Field second-order Møller Plesset (FF MP2) perturbation procedure. According to ab initio quantum mechanical calculations, the title complex exhibits non-zero β values, revealing microscopic second-order NLO behavior. © 2006 Elsevier B.V. All rights reserved.
Yazarlar (5)
1
Hüseyin Ünver
2
Ayhan Elmali
3
Asli Karakas
ORCID: 0000-0002-9034-5840
4
Hulya Kara
5
Emine Donmez
Anahtar Kelimeler
Electric dipole moment
FT-IR
Nickel(II) complex
Static first hyperpolarizability
UV-vis spectroscopy
Kurumlar
Ankara Üniversitesi
Ankara Turkey
Balikesir Üniversitesi
Balikesir Turkey
Selçuk Üniversitesi
Selçuklu Turkey
Scimago Dergi (ISSN Eşleşmesi)
Journal of Molecular Structure
Q2
SJR Skoru0,628
H-Index134
YayıncıElsevier B.V.
ÜlkeNetherlands
Analytical Chemistry (Q2)
Inorganic Chemistry (Q2)
Organic Chemistry (Q2)
Spectroscopy (Q2)
Metrikler
21
Atıf
5
Yazar
5
Anahtar Kelime