Scopus
YÖKSİS DOI Eşleşti
SJR Q2
Synthesis, molecular structure, spectroscopic studies and second-order nonlinear optical behaviour of N,N′-(2-hydroxy-propane-1,3-diyl)-bis(5-nitrosalicylaldiminato-N,O)-copper(II)
Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · Nisan 2007
YÖKSİS Kayıtları
Synthesis molecular structure spectroscopic studies and second order nonlinear optical behaviour of N N 2 hydroxy propane 1 3 diyl bis 5 nitrosalicylaldiminato N O copper II
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy · 2007 SCI-Expanded 6 atıf
Prof. Dr. ASLI KARAKAŞ →
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Makale Bilgileri
ISSN13861425
Yayın TarihiNisan 2007
Cilt / Sayfa66 · 1141-1146
Scopus ID2-s2.0-33847296111
Özet
N,N′-(2-Hydroxy-propane-1,3-diyl)-bis(5-nitrosalicylaldiminato-N,O)-copper(II) has been synthesized. The crystal structure has been determined by X-ray diffraction analysis, and linear optical characterization has been determined by UV-vis spectroscopy. It was found that the molecule under investigation has solvatochromic behaviour in the UV region, implying non-zero microscopic first hyperpolarizability. To reveal the microscopic nonlinear optical (NLO) properties, the static first hyperpolarizabilities (β) and the electric dipole moments (μ) were evaluated by using the ab initio finite field (FF) method. According to the results of the FF calculations, the synthesized compound exhibits non-zero β values, and it might have microscopic NLO behaviour. © 2006 Elsevier B.V. All rights reserved.
Yazarlar (5)
1
Emine Donmez
2
Hulya Kara
3
Asli Karakas
ORCID: 0000-0002-9034-5840
4
Hüseyin Ünver
5
Ayhan Elmali
Anahtar Kelimeler
Copper(II) complex
Crystal structure
Electric dipole moment
Second-order nonlinear optics
UV-vis spectroscopy
Kurumlar
Ankara Üniversitesi
Ankara Turkey
Balikesir Üniversitesi
Balikesir Turkey
Selçuk Üniversitesi
Selçuklu Turkey
Scimago Dergi (ISSN Eşleşmesi)
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Q2
SJR Skoru0,664
H-Index169
YayıncıElsevier B.V.
ÜlkeNetherlands
Analytical Chemistry (Q2)
Atomic and Molecular Physics, and Optics (Q2)
Instrumentation (Q2)
Spectroscopy (Q2)
Metrikler
18
Atıf
5
Yazar
5
Anahtar Kelime