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Quantum chemical calculations and experimental studies of third-order nonlinear optical properties of conjugated TTF-quinones

Optical Materials · Ocak 2013

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YÖKSİS Kayıtları
Quantum chemical calculations and experimental studies of third order nonlinear optical properties of conjugated TTF quinones
Optical Materials · 2013 SCI-Expanded 2 atıf
Prof. Dr. ASLI KARAKAŞ →
YÖKSİS ISSN Eşleşmesi

Bu dergide (ISSN eşleşmesi) kurumun 17 kaydı bulundu.

YÖKSİS Kayıtları — ISSN Eşleşmesi
Colloidal CuZnSnSe4 xSx nanocrystals for hybrid solar cells
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Quantum chemical calculations and experimental studies of third order nonlinear optical properties of conjugated TTF quinones
2013 ISSN: 09253467 SCI-Expanded 2 atıf
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Theoretical and experimental investigations on the nonlinear optical properties of gold III dithiolene complexes
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Ab initio and DFT methodologies for computing hyperpolarizabilities and susceptibilities of highly conjugated organic compounds for nonlinear optical applications
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Makale Bilgileri

ISSN09253467
Yayın TarihiOcak 2013
Cilt / Sayfa36 · 22-26
Özet To investigate microscopic third-order nonlinear optical (NLO) behaviour of two tetrathiafulvalene (TTF) derivatives, TTF-diquinone triad (1) and TTF-monoquinone dyad (2), we have computed both dispersion-free and also dispersion of dipole polarizabilities (α) and third-order hyperpolarizabilities (γ) at 532 nm wavelength using time-dependent Hartree-Fock (TDHF) method. The one-photon absorption (OPA) characterizations of the title molecules have been theoretically obtained by means of configuration interaction (CI) method with all doubly occupied molecular orbitals. We have also calculated the dynamic third-order susceptibilities (χ(3)) using the TDHF method. Our theoretical results on the maximum OPA wavelengths, third-order susceptibilities and corresponding microscopic NLO responses are in good agreement with the previous experimental observations of the examined TTF-based molecules. The highest occupied molecular orbitals (HOMO), the lowest unoccupied molecular orbitals (LUMO) and the HOMO-LUMO band gaps for 1 and 2 have been evaluated by density functional theory (DFT) quantum mechanical calculations at B3LYP/6-31G(d, p) level. © 2013 Elsevier B.V. All rights reserved.

Yazarlar (6)

1
Asli Karakas
ORCID: 0000-0002-9034-5840
2
A. Migalska-Zalas
3
Youssef El kouari
ORCID: 0000-0001-8681-8011
4
Aysun Gozutok
ORCID: 0000-0002-7294-2916
5
Mustafa Karakaya
6
S. Touhtouh

Anahtar Kelimeler

Dipole polarizability Onephoton absorption Third-order hyperpolarizability Third-order susceptibility Time-dependent Hartree-Fock

Kurumlar

Faculté des Sciences d'El Jadida
El Jadida Morocco
Faculté des Sciences et Techniques de Mohammedia
Mohammedia Morocco
J. Dlugosz Academy of Czestochowa
Poland
Selçuk Üniversitesi
Selçuklu Turkey
Scimago Dergi (ISSN Eşleşmesi)
Optical Materials
Q1
SJR Skoru0,654
H-Index136
YayıncıElsevier B.V.
ÜlkeNetherlands
Inorganic Chemistry (Q1)
Atomic and Molecular Physics, and Optics (Q2)
Computer Science (miscellaneous) (Q2)
Electrical and Electronic Engineering (Q2)
Electronic, Optical and Magnetic Materials (Q2)
Organic Chemistry (Q2)
Physical and Theoretical Chemistry (Q2)
Spectroscopy (Q2)
Dergi sayfasına git

Metrikler

26
Atıf
6
Yazar
5
Anahtar Kelime

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