Scopus
YÖKSİS Eşleşti
Proton-coupled oxygen reduction at liquid-liquid interfaces catalyzed by cobalt porphine
Journal of the American Chemical Society · Eylül 2009
YÖKSİS Kayıtları
Proton Coupled Oxygen Reduction at Liquid Liquid Interfaces Catalyzed by Cobalt Porphine
Journal of the American Chemical Society · 2009 SCI-Expanded
PROFESÖR İMREN HATAY PATIR →
Makale Bilgileri
DergiJournal of the American Chemical Society
Yayın TarihiEylül 2009
Cilt / Sayfa131 · 13453-13459
Scopus ID2-s2.0-70349400755
Özet
Cobalt porphine (CoP) dissolved in the organic phase of a biphasic system is used to catalyze O2 reduction by an electron donor, ferrocene (Fc). Using voltammetry at the interface between two immiscible electrolyte solutions (ITIES), it is possible to drive this catalytic reduction at the interface as a function of the applied potential difference, where aqueous protons and organic electron donors combine to reduce O2. The current signal observed corresponds to a proton-coupled electron transfer (PCET) reaction, as no current and no reaction can be observed in the absence of either the aqueous acid, CoP, Fc, or O2. © 2009 American Chemical Society.
Yazarlar (10)
1
Imren Hatay Patir
ORCID: 0000-0003-2937-6557
2
Bin Su
3
Fei Li
4
Manuel Mendez
5
Tony Khoury
6
Claude P. Gros
7
Jean Michel Barbe
8
Mustafa Ersöz
9
Zdeněk Samec
10
Hubert H. Girault
Kurumlar
École Polytechnique Fédérale de Lausanne
Lausanne Switzerland
ICMUB Institut de Chimie Moléculaire de l'Université de Bourgogne
Dijon France
J. Heyrovsky Institute of Physical Chemistry of the Academy of Sciences of the Czech Republic
Prague Czech Republic
Selçuk Üniversitesi
Selçuklu Turkey
Metrikler
101
Atıf
10
Yazar