Scopus
YÖKSİS DOI Eşleşti
SJR Q1
Molecular electrocatalysis for oxygen reduction by cobalt porphyrins adsorbed at liquid/liquid interfaces
Journal of the American Chemical Society · Şubat 2010
YÖKSİS Kayıtları
Molecular Electrocatalysis for Oxygen Reduction by Cobalt Porphyrins Adsorbed at Liquid Liquid Interfaces
Journal of the American Chemical Society · 2010 SCI-Expanded
Prof. Dr. İMREN HATAY PATIR →
YÖKSİS Kayıtları — ISSN Eşleşmesi
Oxygen Reduction Catalyzed by a Fluorinated Tetraphenylporphyrin Free Base at Liquid Liquid Interfaces
2010 ISSN: 0002-7863 SCI-Expanded
Prof. Dr. İMREN HATAY PATIR →
Molecular Electrocatalysis for Oxygen Reduction by Cobalt Porphyrins Adsorbed at Liquid Liquid Interfaces
2010 ISSN: 0002-7863 SCI-Expanded
Prof. Dr. İMREN HATAY PATIR →
Proton Coupled Oxygen Reduction at Liquid Liquid Interfaces Catalyzed by Cobalt Porphine
2009 ISSN: 0002-7863 SCI-Expanded
Prof. Dr. İMREN HATAY PATIR →
Makale Bilgileri
ISSN00027863
Yayın TarihiŞubat 2010
Cilt / Sayfa132 · 2655-2662
Scopus ID2-s2.0-77649289969
Özet
Molecular electrocatalysis for oxygen reduction at a polarized water/1,2-dichloroethane (DCE) interface was studied, involving aqueous protons, ferrocene (Fc) in DCE and amphiphilic cobalt porphyrin catalysts adsorbed at the interface. The catalyst, (2,8,13,17-tetraethyl-3,7,12,18-tetramethyl-5-p- amino-phenylporphyrin) cobalt(II) (CoAP), functions like conventional cobalt porphyrins, activating O2 via coordination by the formation of a superoxide structure. Furthermore, due to the hydrophilic nature of the aminophenyl group, CoAP has a strong affinity for the water/DCE interface as evidenced by lipophilicity mapping calculations and surface tension measurements, facilitating the protonation of the CoAP-O2 complex and its reduction by ferrocene. The reaction is electrocatalytic as its rate depends on the applied Galvani potential difference between the two phases. © 2010 American Chemical Society.
Yazarlar (10)
1
Bin Su
2
Imren Hatay Patir
ORCID: 0000-0003-2937-6557
3
Antonín Trojánek
4
Zdeněk Samec
5
Tony Khoury
6
Claude P. Gros
7
Jean Michel Barbe
8
Antoine Daina
9
Pierre Alain Carrupt
10
Hubert H. Girault
Kurumlar
École Polytechnique Fédérale de Lausanne
Lausanne Switzerland
ICMUB Institut de Chimie Moléculaire de l'Université de Bourgogne
Dijon France
J. Heyrovsky Institute of Physical Chemistry of the Academy of Sciences of the Czech Republic
Prague Czech Republic
Section des Sciences Pharmaceutiques
Geneve Switzerland
Selçuk Üniversitesi
Selçuklu Turkey
Son Atıflar
Comprehensive review of molecular oxygen activation technology: strategies, organic pollutants removal and other innovative applications
Separation and Purification Technology
· 2026 · DOI
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· 2025 · DOI
Selective two-electron and four-electron oxygen reduction reactions using Co-based electrocatalysts
Chemical Society Reviews
· 2025 · DOI
Recent advances in the design of SERS substrates and sensing systems for (bio)sensing applications: Systems from single cell to single molecule detection
F1000research
· 2025 · DOI
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· 2024 · DOI
Unraveling Meso-Substituent Steric Effects on the Mechanism of Hydrogen Evolution Reaction in NiII Porphyrin Hydrides Using DFT Method
Molecules
· 2024 · DOI
Structural and electronic properties of Li-adsorbed single and bilayer porphyrin sheets as an electrode material for energy storage devices - a DFT analysis
Physical Chemistry Chemical Physics
· 2024 · DOI
Tailoring the cobalt porphyrin for minimal overpotential in the electrochemical oxygen evolution/reduction reactions: A density functional study
International Journal of Hydrogen Energy
· 2023 · DOI
Performance Evolution of Typical Electrocatalysts with Electrolyte Temperature during Alkaline Water Electrolysis
Journal of Physical Chemistry C
· 2023 · DOI
Potential-Modulated Ion Distributions in the Back-to-Back Electrical Double Layers at a Polarised Liquid|Liquid Interface Regulate the Kinetics of Interfacial Electron Transfer
Chemelectrochem
· 2023 · DOI
Scimago Dergi (ISSN Eşleşmesi)
Journal of the American Chemical Society
Q1
OA
SJR Skoru5,491
H-Index759
YayıncıAmerican Chemical Society
ÜlkeUnited States
Biochemistry (Q1)
Catalysis (Q1)
Chemistry (miscellaneous) (Q1)
Colloid and Surface Chemistry (Q1)
Metrikler
141
Atıf
10
Yazar