Scopus
🔓 Açık Erişim YÖKSİS Eşleşti
Biphasic water splitting by osmocene
Proceedings of the National Academy of Sciences of the United States of America · Temmuz 2012
YÖKSİS Kayıtları
Biphasic water splitting by osmocene
Proceedings of the National Academy of Sciences · 2012 SCI-Expanded
PROFESÖR İMREN HATAY PATIR →
Makale Bilgileri
DergiProceedings of the National Academy of Sciences of the United States of America
Yayın TarihiTemmuz 2012
Cilt / Sayfa109 · 11558-11563
Scopus ID2-s2.0-84961982042
Erişim🔓 Açık Erişim
Özet
The photochemical reactivity of osmocene in a biphasic waterorganic solvent system has been investigated to probe its water splitting properties. The photoreduction of aqueous protons to hydrogen under anaerobic conditions induced by osmocene dissolved in 1,2-dichloroethane and the subsequent water splitting by the osmocenium metal-metal dimer formed during H2 production were studied by electrochemical methods, UV-visible spectrometry, gas chromatography, and nuclear magnetic resonance spectroscopy. Density functional theory computations were used to validate the reaction pathways.
Yazarlar (9)
1
Peiyu Ge
2
Tanya K. Todorova
3
Imren Hatay Patir
ORCID: 0000-0003-2937-6557
4
Astrid J. Olaya
5
Heron Vrubel
6
Manuel Mendez
7
Xile Hu
8
Clémence Corminboeuf
9
Hubert H. Girault
Kurumlar
École Polytechnique Fédérale de Lausanne
Lausanne Switzerland
Metrikler
39
Atıf
9
Yazar