Scopus
YÖKSİS Eşleşti
Oxygen reduction catalyzed by aniline derivatives at liquid/liquid interfaces
Journal of Electroanalytical Chemistry · Ekim 2012
YÖKSİS Kayıtları
Oxygen reduction catalyzed by aniline derivatives at liquid liquid interfaces
Journal of Electroanalytical Chemistry · 2012 SCI-Expanded
PROFESÖR İMREN HATAY PATIR →
Makale Bilgileri
DergiJournal of Electroanalytical Chemistry
Yayın TarihiEkim 2012
Cilt / Sayfa685 · 28-32
Scopus ID2-s2.0-84866722261
Özet
Oxygen reduction reaction (ORR) by decamethylferrocene (DMFc) at a water/1,2-dichloroethane (DCE) interface proceeds as a proton coupled electron transfer process, with the supply of protons by the aqueous phase and electrons by the electron donor DMFc in the organic phase. In the present work, the reduction of oxygen by DMFc has been investigated in the presence of different aniline derivatives such as 3,5,N,N-Tetramethylaniline (TMA), N,N-Diethylaniline (DEA), 4-Nitroaniline (4-NA), 4-Dodecylaniline (4-DA) which act as proton ionophores to transfer protons from the aqueous to the organic phase. It has been found that ORR by DMFc can be catalyzed efficiently by the use of aniline derivatives depending on their basicity strength which follows an order of DEA > TMA > 4-DA > 4- NA. © 2012 Elsevier B.V. All rights reserved.
Yazarlar (1)
1
Imren Hatay Patir
ORCID: 0000-0003-2937-6557
Anahtar Kelimeler
Aniline derivatives
Decamethylferrocene
Liquid/liquid interface
Oxygen reduction
Kurumlar
Selçuk Üniversitesi
Selçuklu Turkey
Metrikler
11
Atıf
1
Yazar
4
Anahtar Kelime