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Use of polymer-free calixarene nanofibers in heavy metal extractions

Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017 · Aralık 2017

Makale Bilgileri

DergiProceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017
Yayın TarihiAralık 2017
Cilt / Sayfa2017-January
Özet Polymer free calix[4]arene nanofibers were prepared via new electrospinning method with metal ion adsorption capacity. Two different calix[4]arene derivatives (compound 2 and 3) containing amide functionalities were used in this study, which were fully characterized by HNMR, FTIR and elemental analysis. Calix[4]arene nanofibers were analyzed with different surface characterization techniques such as SEM, TEM and AFM. SEM images of compound 2 and 3 nanofibers reveals there are non-bonded randomly grown fibers with average fiber diameter (AFD) was in the range of 237 to 307 nm for compoud 2 and 203-280 nm for compound. Adsorption study show the SEM-EDX mapping show adsorption of different metal ions (Hg+2, Pb+2, Cu+2, Co+2, Cd+2, Ni+2) on nanofibers. The the adsorption study show Hg+2, Pb+2 and Cu+2 adsorbed on nanofibers particularly at high pH. The maximum adsorption (98 %) was observed at pH 2 for Hg+2.

Yazarlar (2)

1
Fatih Ozcan
2
Seref Ertul

Anahtar Kelimeler

adsorpsion calixarene nanofiber electrospinning heavy metal

Kurumlar

Advanced Technology Research and Application Center
Konya Turkey
Selçuk Üniversitesi
Selçuklu Turkey