Scopus
🔓 Açık Erişim YÖKSİS Eşleşti
Crystal structure of trans-diaquabis(4-cyanobenzoato-κO)bis(N,N-diethylnicotinamide-κN)cadmium
Acta Crystallographica Section E: Crystallographic Communications · Ocak 2016
YÖKSİS Kayıtları
Crystal structure oftrans-diaquabis(4-cyanobenzoato-κO)bis(N,N-diethylnicotinamide-κN)cadmium
Acta Crystallographica Section E Crystallographic Communications · 2016 ESCI
PROFESÖR NURCAN AKDURAN →
Makale Bilgileri
DergiActa Crystallographica Section E: Crystallographic Communications
Yayın TarihiOcak 2016
Cilt / Sayfa72 · 1827-1829
Scopus ID2-s2.0-85003682293
Erişim🔓 Açık Erişim
Özet
The mononuclear title cadmium complex, [Cd(C10H14N2O)2(C8H4NO2)2(H2O)2], is centrosymmetric and contains two water molecules, two 4-cyanobenzoate (CB) ligands and two diethylnicotinamide (DENA) ligands. All the ligands are coordinated to the CdII atom in a monodentate mode. The four nearest O atoms around the CdII atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination sphere being completed by the two pyridine N atoms of the DENA ligands at distances of 2.3336(13)Å. The dihedral angle between the carboxylate group and the adjacent benzene ring is 8.75(16)°, while the benzene and pyridine rings are oriented at a dihedral angle of 57.83(5)°. The water molecules exhibit both intramolecular [to the non-coordinating carboxylate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.670(2)Å] and intermolecular [to the amide carbonyl O atom, enclosing an R 2 2(16) ring motif, where O⋯O = 2.781(2)Å] O - H⋯O hydrogen bonds. The latter lead to the formation of supramolecular chains propagating along [110].
Yazarlar (5)
1
Nurcan Akduran
2
Mustafa Sertçelik
3
Ömer Aydoǧdu
4
Hacali Necefoǧlu
5
Tuncer Hökelek
Anahtar Kelimeler
cadmium
crystal structure
transition metal complexes of benzoic acid and nicotinamide derivatives
Kurumlar
Baku State University
Baku Azerbaijan
Hacettepe Üniversitesi
Ankara Turkey
Kafkas Üniversitesi
Kars Turkey
SANAEM
Kazan Turkey
Metrikler
3
Atıf
5
Yazar
3
Anahtar Kelime