Scopus
🔓 Açık Erişim YÖKSİS Eşleşti
Crystal structure of bis-(μ-3-nitro-benzoato)-κ<sup>3</sup> O,O′:O;κ<sup>3</sup> O:O,O′-bis-[bis-(3-cyano-pyridine-κN <sup>1</sup>)(3-nitro-benzoato-κ<sup>2</sup> O,O′)cadmium]
Acta Crystallographica Section E: Crystallographic Communications · Ocak 2017
YÖKSİS Kayıtları
Crystal structure of bis(μ-3-nitrobenzoato)-κ3O,O\u2032:O;κ3O:O,O\u2032-bis[bis(3-cyanopyridine-κN1)(3-nitrobenzoato-κ2O,O\u2032)cadmium]
Acta Crystallographica Section E Crystallographic Communications · 2017 ESCI
PROFESÖR NURCAN AKDURAN →
Makale Bilgileri
DergiActa Crystallographica Section E: Crystallographic Communications
Yayın TarihiOcak 2017
Cilt / Sayfa73 · 413-416
Scopus ID2-s2.0-85014661142
Erişim🔓 Açık Erişim
Özet
The asymmetric unit of the title compound, [Cd2(C7H4NO4)4(C6H4N2)4], contains one CdII atom, two 3-nitro-benzoate (NB) anions and two 3-cyano-pyridine (CPy) ligands. The two CPy ligands act as monodentate N(pyridine)-bonding ligands, while the two NB anions act as bidentate ligands through the carboxyl-ate O atoms. The centrosymmetric dinuclear complex is generated by application of inversion symmetry, whereby the CdII atoms are bridged by the carboxyl-ate O atoms of two symmetry-related NB anions, thus completing the distorted N2O5 penta-gonal-bipyramidal coordination sphere of each CdII atom. The benzene and pyridine rings are oriented at dihedral angles of 10.02 (7) and 5.76 (9)°, respectively. In the crystal, C - H...N hydrogen bonds link the mol-ecules, enclosing R 2 2(26) ring motifs, in which they are further linked via C - H...O hydrogen bonds, resulting in a three-dimensional network. In addition, π-π stacking inter-actions between parallel benzene rings and between parallel pyridine rings of adjacent mol-ecules [shortest centroid-to-centroid distances = 3.885 (1) and 3.712 (1) Å, respectively], as well as a weak C - H...π inter-action, may further stabilize the crystal structure.
Yazarlar (5)
1
Tuncer Hökelek
2
Nurcan Akduran
3
Azer Ozen
4
Guventurk Ugurlu
5
Hacali Necefoǧlu
Anahtar Kelimeler
benzoic acid
cadmium
crystal structure
transition metal complex
Kurumlar
Baku State University
Baku Azerbaijan
Hacettepe Üniversitesi
Ankara Turkey
Kafkas Üniversitesi
Kars Turkey
SANAEM
Kazan Turkey
Metrikler
2
Atıf
5
Yazar
4
Anahtar Kelime