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New tridentate azo-azomethines and their copper(II) complexes: Synthesis, solvent effect on tautomerism, electrochemical and biological studies

Journal of Molecular Structure · Eylül 2015

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YÖKSİS Kayıtları
New tridentate azo azomethines and their copper II complexes Synthesis solvent effect on tautomerism electrochemical and biological studies
Journal of Molecular Structure · 2015 SCI-Expanded 2 atıf
PROFESÖR UĞUR ARSLAN →
New tridentate azo azomethines and their copper II complexes Synthesis solvent effect on tautomerism electrochemical and biological studies
Journal of Molecular Structure · 2015 SCI
PROFESÖR PERVİN SOYLU →
New tridentate azo azomethines and their copper II complexes Synthesis solvent effect on tautomerism electrochemical and biological studies
Journal of Molecular Structure · 2015 SCI
PROFESÖR HATİCE TÜRK DAĞI →
New tridentate azo azomethines and their copper II complexes Synthesis solvent effect on tautomerism electrochemical and biological studies
Journal of Molecular Structure · 2015 SCI-Expanded
PROFESÖR UĞUR ARSLAN →

Makale Bilgileri

DergiJournal of Molecular Structure
Yayın TarihiEylül 2015
Cilt / Sayfa1096 · 64-73
Özet In this study, three azo-azomethines and their copper(II) complexes were prepared and characterized by analytical and spectroscopic methods. The complexes prepared were found to be mononuclear and the chelation of the ligands to the copper(II) ions occurs through two phenolic oxygens and a nitrogen atom of the azomethine group of the ligand. The tautomeric behaviors of the azo-azomethines in solution were studied by UV-Vis. spectra in three organic solvents with different polarity (CHCl<inf>3</inf>, DMSO and DMF) at room temperature. The redox behaviors of the azo-azomethines and their Cu(II) complexes were investigated by cyclic voltammetry (CV) in DMSO solution containing 0.1 M tetrabutylammonium tetrafluoroborate (TBATFB) as supporting electrolyte. Additionally, the antibacterial activity was also evaluated by the broth microdilution methods against Staphylococcus aureus, Enterococcus faecalis, Escherichia coli, Klebsiella pneumoniae and Pseudomonas aeruginosa. The compounds were found to be less effective against all bacteria tested than two reference antibiotics (ampicillin and gentamicin).

Yazarlar (6)

1
Münire Sarigul
2
P. Deveci
3
Muhammet Kose
4
Ugur Arslan
5
Hatice Türk Dağı
6
Mukerrem Kurtoglu

Anahtar Kelimeler

Antibacterial activity Azo-azomethines Copper(II) complexes Cyclic voltammetry Solvent effect Tautomer

Kurumlar

Kahramanmaras Sütçü Imam Üniversitesi
Kahramanmaras Turkey
Selçuk Üniversitesi
Selçuklu Turkey

Metrikler

45
Atıf
6
Yazar
6
Anahtar Kelime

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