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Optimization of selective leaching of Zn from electric arc furnace steelmaking dust using response surface methodology

Transactions of Nonferrous Metals Society of China English Edition · Ağustos 2015

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YÖKSİS Kayıtları
Optimization of selective leaching of Zn from electric arc furnace steelmaking dust using response surface methodology
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA · 2015 SCI
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Makale Bilgileri

DergiTransactions of Nonferrous Metals Society of China English Edition
Yayın TarihiAğustos 2015
Cilt / Sayfa25 · 2753-2762
Özet The aim of this work is to investigate and optimize the effects of the leaching parameters on the selective leaching of zinc from electric arc furnace steelmaking dust (EAFD). The response surface method was applied on the basis of a three-level Box-Behnken experimental design method for optimization of selective leaching parameters of zinc from EAFD. The leaching recoveries of zinc (Y<inf>Zn</inf>) and iron (Y<inf>Fe</inf>) were taken as the response variables, where the concentration of sulphuric acid (X<inf>1</inf>, mol/L), leaching temperature (X<inf>2</inf>, °C), leaching time (X<inf>3</inf>, min), and liquid/solid ratio (X<inf>4</inf>, mL/g) were considered as the independent variables (factors). The mathematical model was proposed. Statistical ANOVA analysis and confirmation tests were applied. A maximum of 79.09% of zinc was recovered while the minimum iron recovery was 4.08% under the optimum conditions of leaching time 56.42 min, H<inf>2</inf>SO<inf>4</inf> concentration 2.35 mol/L, leaching temperature 25 °C and liquid/solid ratios. By using ANOVA, the most influential factors on leaching of zinc and iron were determined as H<inf>2</inf>SO<inf>4</inf> concentration and leaching temperature, respectively. The proposed model equations using response surface methodology show good agreement with the experimental data, with correlation coefficients (R<sup>2</sup>) of 0.98 for zinc recovery and 0.97 for iron recovery.

Yazarlar (5)

1
Mehmet Kul
2
Kürşad Oʇuz Oskay
3
Mehmet Şimşir
4
Halit Sübütay
5
Habip Kirgezen

Anahtar Kelimeler

Box-Behnken design EAFD iron optimization selective leaching zinc

Kurumlar

Cumhuriyet Üniversitesi
Sivas Turkey

Metrikler

59
Atıf
5
Yazar
6
Anahtar Kelime