Scopus
YÖKSİS DOI Eşleşti
SJR Q2
Fully Automated Three-Dimensional Column-Switching SPE-FIA-HPLC System for the Characterization of Lipids by a Single Injection: Part I. Instrumental Design and Chemometric Approach to Assess the Effect of Experimental Settings on the Response of ELSD
JAOCS Journal of the American Oil Chemists Society · Ocak 2016
YÖKSİS Kayıtları
Fully Automated Three Dimensional Column Switching SPE FIA HPLC System for the Characterization of Lipids by a Single Injection Part I Instrumental Design and Chemometric Approach to Assess the Effect of Experimental Settings on the Response of ELSD
Journal of the American Oil Chemists' Society · 2016 SCI-Expanded
Prof. Dr. HÜSEYİN KARA →
YÖKSİS Kayıtları — ISSN Eşleşmesi
Determination of Fatty Acid Profiles and Esterase Activities in the Gills and Gonads of Vimba vimba L 1758
2015 ISSN: 0003-021X SSCI
Prof. Dr. GÖKHAN ZENGİN →
Evaluation of the Triglyceride Composition of Pomegranate Seed Oil by RP HPLC Followed by GC MS
2015 ISSN: 0003-021X SCI-Expanded
Prof. Dr. HÜSEYİN KARA →
A Chemometric Approach to Assess the Frying Stability of Cottonseed Oil Blends During Deep Frying Process I Polar and Polymeric Compound Analyses
2013 ISSN: 0003-021X SCI-Expanded
Doç. Dr. İSMAİL TARHAN →
Chemical Compositions and Mineral Contents of Some Hull Less Pumpkin Seed and Oils
2016 ISSN: 0003-021X SCI-Expanded
Doç. Dr. MUSA SEYMEN →
Fully Automated Three Dimensional Column Switching SPE FIA HPLC System for the Characterization of Lipids by a Single Injection Part I Instrumental Design and Chemometric Approach to Assess the Effect of Experimental Settings on the Response of ELSD
2016 ISSN: 0003-021X SCI-Expanded
Prof. Dr. HÜSEYİN KARA →
Chemical Compositions and Mineral Contents of Some Hull Less Pumpkin Seed and Oils
2016 ISSN: 0003-021X SCI-Expanded
Prof. Dr. ÖNDER TÜRKMEN →
A Highly Efficient Automated Flow Injection Method for Rapid Determination of Free Fatty Acid Content in Corn Oils
2014 ISSN: 0003-021X SCI-Expanded
Prof. Dr. HÜSEYİN KARA →
A Chemometric Approach to Assess the Frying Stability of Cottonseed Oil Blends During Deep Frying Process I Polar and Polymeric Compound Analyses
2013 ISSN: 0003-021X SCI-Expanded
Prof. Dr. HÜSEYİN KARA →
A Chemometric Approach to Assess the Frying Stability of Cottonseed Oil Blends During Deep Frying Process I Polar and Polymeric Compound Analyses
2013 ISSN: 0003-021X SCI-Expanded 1 atıf
Prof. Dr. HAMİDE FİLİZ AYYILDIZ →
A Highly Efficient Automated Flow Injection Method for Rapid Determination of Free Fatty Acid Content in Corn Oils
2014 ISSN: 0003-021X SCI-Expanded 1 atıf
Prof. Dr. HAMİDE FİLİZ AYYILDIZ →
Effect of roasting on the physico‐chemical properties, fatty acids, polyphenols and mineral contents of tobacco (Nicotiana tabacum L.) seed and oils
2023 ISSN: 0003-021X SCI-Expanded Q3
Doç. Dr. NURHAN USLU →
Effect of roasting on the physico-chemical properties,
fatty acids, polyphenols and mineral contents of tobacco
(Nicotiana tabacum L.) seed and oils
2023 ISSN: 0003-021X SCI-Expanded Q3
Prof. Dr. SAİT GEZGİN →
Effect of roasting on the physico‐chemical properties, fatty acids, polyphenols and mineral contents of tobacco (Nicotiana tabacum L.) seed and oils
2023 ISSN: 0003-021X SCI-Expanded Q3
Prof. Dr. SAİT GEZGİN →
Effect of microwave and oven roasting on chemical composition, bioactive properties, phenolic compounds and fatty acid compositions of sunflower seed and oils
2024 ISSN: 0003-021X SCI-Expanded
Doç. Dr. NURHAN USLU →
Makale Bilgileri
ISSN0003021X
Yayın TarihiOcak 2016
Cilt / Sayfa93 · 11-26
Scopus ID2-s2.0-84953358392
Özet
This article presents the first application of fully automated three-dimensional (3D) column-switching SPE-FIA-HPLC system for the characterization of lipids by a single injection. The whole system was designed and set up by modifying Agilent 1200 Series HPLC system in our laboratory. By using this system, a complete separation profile of the oil samples was achieved in a very short time period by using single injections. This approach was applied on vegetable oils which contains a large number of relatively high-class lipid components, such as TG, FFA, sterols, tocopherols, DG, ester and MG. In this part of the study, we focused on the optimization of evaporative light scattering detector (ELSD) by using an experimental design and RSM. Three experimental parameters were chosen as an independent variables which are the flow rate of mobile phase, nebulization temperature and evaporation temperature. A multivariate five level experimental design was used to establish a quadratic model as a functional relationship between the response values and independent variables. The optimal values of parameters were found to be a flow rate of 1.25 mL min-1, nebulization temperature of 80 °C, and evaporation temperature of 40 °C. Regression analysis with an R 2 values indicated as a satisfactory correlation between the experimental and predicted values. ANOVA test results were also illustrate that the models can be successfully used to predict the optimum parameters of ELSD. Thus, the proposed system is suitable for a large number of applications including research and development of new quality control and characterization methods for vegetable oils.
Yazarlar (2)
1
Fatma Nur Arslan
2
Huseyin Kara
Anahtar Kelimeler
Chemometric
Column-switching
ELSD
Lipid
Three-dimensional (3D) separation
Vegetable oil
Kurumlar
Karamanoğlu Mehmetbey Üniversitesi
Karaman Turkey
Necmettin Erbakan Üniversitesi
Meram Turkey
Selçuk Üniversitesi
Selçuklu Turkey
Scimago Dergi (ISSN Eşleşmesi)
JAOCS, Journal of the American Oil Chemists' Society
Q2
SJR Skoru0,523
H-Index145
YayıncıJohn Wiley and Sons Inc
ÜlkeGermany
Chemical Engineering (miscellaneous) (Q2)
Food Science (Q2)
Organic Chemistry (Q2)
Process Chemistry and Technology (Q3)
Metrikler
6
Atıf
2
Yazar
6
Anahtar Kelime