Scopus
YÖKSİS Eşleşti
Investigation of the homonuclear and polynuclear complexes of Fe<sup>III</sup> of pentadentate dipodal s-triazine Schiff base ligand
Polyhedron · Aralık 2024
YÖKSİS Kayıtları
Investigation of the homonuclear and polynuclear complexes of FeIII of pentadentate dipodal s-triazine Schiff base ligand
Polyhedron · 2024 SCI-Expanded
PROFESÖR ZİYA ERDEM KOÇ →
Makale Bilgileri
DergiPolyhedron
Yayın TarihiAralık 2024
Cilt / Sayfa264
Scopus ID2-s2.0-85207595112
Özet
An efficient synthesis of a new class of “Dipodal s-triazine Schiff base ligand” has been developed based on high-yielding amines substitutions of 2-vinyl-4,6-diamino-1,3,5-triazine (acryloguanamine) (VDAT) by salicylaldehyde. A new compound characterized by a dipodal s-triazine pentadentate Schiff base with 2-vinyl-4,6-N,N’-bis(2,4-dihydroxybenzylidine)-1,3,5-triazine [VDAT24] has been developed. The obtained [VDAT24] was polymerized to obtain poly(2-vinyl-4,6-N,N’-bis(2,4-dihydroxybenzylidine)-1,3,5-triazine) [PVDAT24]. Subsequently, s-Triazine-centered Fe(III) homonuclear complexes [VDAT24Fe], and polynuclear complexes [PVDAT24Fe] were obtained derived. As a result, the ligand obtained by elemental analysis, ICP-AES, TGA, FTIR, 1H NMR and 13C NMR. Isolated ligand complex, FTIR, TGA, and were illuminated structures on the magnetic susceptibility. The resulting two different polymeric ligands and certain complexes of FTIR, TGA, and Ostwald Viscometer elucidated the structures of magnetic susceptibility.
Yazarlar (2)
1
Remziye Beyza Arslan
2
Ziya Erdem Koç
Anahtar Kelimeler
2-Vinyl-4,6-diamino-1,3,5-triazine
Acriloguanamin
Metal complexes
Polymeric s-triazine
Schiff base
Kurumlar
Selçuk Üniversitesi
Selçuklu Turkey