Scopus
YÖKSİS Eşleşti
The investigation of complexation properties and synthesis of the (salen and salophen)-bridged Fe/Cr(III) capped complexes of novel Schiff bases
Journal of Inclusion Phenomena and Macrocyclic Chemistry · Ocak 2010
YÖKSİS Kayıtları
The investigation of complexation properties and synthesis of the salen and salophen bridged Fe Cr III capped complexes of novel Schiff bases
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY · 2010 SCI-Expanded 7 atıf
PROFESÖR ERSİN GÜLER →
The investigation of complexation properties and synthesis of the salen and salophen bridged Fe Cr III capped complexes of novel Schiff bases
Journal of Inclusion Phenomena and Macrocyclic Chemistry · 2010 SCI-Expanded 6 atıf
PROFESÖR ERSİN GÜLER →
The investigation of complexation properties and synthesis of the salen and salophen bridged Fe Cr III capped complexes of novel Schiff bases
Journal of Inclusion Phenomena and Macrocyclic Chemistry · 2010 SCI-Expanded 6 atıf
PROFESÖR ÖZCAN KOÇYİĞİT →
Makale Bilgileri
DergiJournal of Inclusion Phenomena and Macrocyclic Chemistry
Yayın TarihiOcak 2010
Cilt / Sayfa67 · 29-37
Scopus ID2-s2.0-77952322064
Özet
This article describes synthesis of novel Schiff base and its complexation properties with Fe(III) and Cr(III). Firstly 1,3,5-tris (formylphenoxymethyl)benzene (1, TRIPOD) with tris aldehyde groups were synthesized using the 1,3,5-trisbromomethylbenzene and 4-hydroxybezaldehyde. The compound 1 was converted to the Schiff base derivative (2, TCPIM-TRIPOD) with p-aminobenzoic acid. The prepared TCPIM-TRIPOD were reacted with four new trinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N-bis(salicylidene)ethylenediamine-(salenH2) or bis(salicylidene)-o-phenylenediamine-(salophenH2) and characterized by means of elemental analysis carrying out infrared spectroscopy (IR), thermogravimetric analysis (TG), nuclear magnetic resonance (1H-NMR), elemental analysis and magnetic susceptibility measurement. The complexes can also be characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by carboxylic acids. The tricarboxylic acids play a role as bridges for weak antiferromagnetic intramolecular exchange. © 2009 Springer Science+Business Media B.V.
Yazarlar (2)
1
Ozcan Kocyigit
2
Ersin Guler
Anahtar Kelimeler
Complexation
Schiff base
Trisaldehyde
Trisbromomethylbenzene
Kurumlar
Selçuk Üniversitesi
Selçuklu Turkey
Metrikler
16
Atıf
2
Yazar
4
Anahtar Kelime