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Synthesis of new water-soluble phosphonate calixazacrowns and their use as drug solubilizing agents

Journal of Inclusion Phenomena and Macrocyclic Chemistry · Aralık 2012

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YÖKSİS Kayıtları
Synthesis of new water soluble phosphonate calixazacrowns and their use as drug solubilizing agents
Journal of Inclusion Phenomena and Macrocyclic Chemistry · 2012 SCI-Expanded 5 atıf
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Makale Bilgileri

DergiJournal of Inclusion Phenomena and Macrocyclic Chemistry
Yayın TarihiAralık 2012
Cilt / Sayfa74 · 293-303
Özet This study presents the selective chloromethylation of calix[4](aza)crown ethers 2a-c, using chloromethyl n-octyl ether and SnCl 4 in chloroform at room temperature in good yield for the first time. Chloromethylated products 2a-c are used as key intermediates to synthesize new water-soluble p-phosphonato calix[4](aza)crown ethers 5a-c. Liquid-liquid phase extraction and phase solubility studies with poor water soluble drug molecules such as nifedipine, niclosamide and furosemide are performed to evaluate their binding properties. Among the studied drugs, furosemide was the most effectively dissolved drug by p-phosphonato calix[4](aza)crown ethers 5a-c in water. © 2012 Springer Science+Business Media B.V.

Yazarlar (3)

1
Mevlut Bayrakci
2
Seref Ertul
3
Mustafa Yilmaz

Anahtar Kelimeler

Calixarene Chloromethylation Furosemide Niclosamide Nifedipine

Kurumlar

Niğde Ömer Halisdemir University
Nigde Turkey
Selçuk Üniversitesi
Selçuklu Turkey

Metrikler

16
Atıf
3
Yazar
5
Anahtar Kelime

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