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A calix[4]arene derivative-doped perchlorate-selective membrane electrodes with/without multi-walled carbon nanotubes

Ionics · Nisan 2017

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YÖKSİS Kayıtları
A calix[4]arene derivative-doped perchlorate-selective membrane electrodes with/without multi-walled carbon nanotubes
Ionics · 2017 SCI
Prof. Dr. MUSTAFA YILMAZ →
YÖKSİS ISSN Eşleşmesi

Bu dergide (ISSN eşleşmesi) kurumun 5 kaydı bulundu.

YÖKSİS Kayıtları — ISSN Eşleşmesi
Second and third-order nonlinear optical behavior of natural pigment: chlorophyll and crocin
2017 ISSN: 0947-7047 SCI-Expanded Q2
Prof. Dr. ASLI KARAKAŞ →
A calix[4]arene derivative-doped perchlorate-selective membrane electrodes with/without multi-walled carbon nanotubes
2017 ISSN: 0947-7047 SCI
Prof. Dr. MUSTAFA YILMAZ →
Second and third-order nonlinear optical behavior of natural pigment: chlorophyll and crocin
2017 ISSN: 0947-7047 SCI-Expanded
Prof. Dr. YUSUF CEYLAN →
A calix[4]arene derivative-doped perchlorate-selective membrane electrodes with/without multi-walled carbon nanotubes
2017 ISSN: 0947-7047 SCI-Expanded
Prof. Dr. ÖZLEM ŞAHİN →
Second and third-order nonlinear optical behavior of natural pigment: chlorophyll and crocin
2017 ISSN: 0947-7047 SCI-Expanded
Prof. Dr. YUSUF CEYLAN →

Makale Bilgileri

Dergi Ionics
ISSN09477047
Yayın TarihiNisan 2017
Cilt / Sayfa23 · 917-927
Özet In this study, poly (vinyl chloride)(PVC) membrane electrodes with/without multi-walled carbon nanotubes (MWCNTs) based on a calix[4]arene derivative for perchlorate ion were described. The influence of membrane composition, pH, conditioning solution on the potentiometric response of the electrodes was investigated. Perchlorate-selective PVC membrane electrode exhibited a slope of 47.8 ± 0.6 mV/pClO4 in the range of 1.0 × 10−7–1.0 × 10−1 mol L−1at pH 4.0 while the coated Pt electrodes with MWCNT-OH, MWCNT-COOH and MWCNT displayed slopes of 46.1 ± 0.7 mV/pClO4 (5.0 × 10−6–1.0 × 10−1 mol L−1), 50.4 ± 1.9 mV/pClO4 (1.0 × 10−6–1.0 × 10−1 mol L−1) and 44.4 ± 0.3 mV/pClO4 (1.0 × 10−5–1.0 × 10−1 mol L−1), respectively. Other response characteristics of these electrodes such as response time, lifetime and detection limit were identified, and the selectivity coefficients towards various anions were calculated by separate solution method. Moreover, the perchlorate-selective electrodes described here were successfully used as an indicator electrode for the determination of perchlorate in real samples such as tap water, river water and human urine by direct calibration method.

Yazarlar (5)

1
H. Elif Kormalı Ertürün
2
Ayça Demirel Özel
3
Melek Nur Ayanoğlu
4
Ozlem Sahin
5
Mustafa Yilmaz

Anahtar Kelimeler

Calix[4]arene Perchlorate determination Perchlorate-selective electrode Potentiometry

Kurumlar

Ankara Üniversitesi
Ankara Turkey
Selçuk Üniversitesi
Selçuklu Turkey
Scimago Dergi (ISSN Eşleşmesi)
Ionics
Q2
SJR Skoru0,517
H-Index86
YayıncıSpringer Science and Business Media Deutschland GmbH
ÜlkeGermany
Chemical Engineering (miscellaneous) (Q2)
Engineering (miscellaneous) (Q2)
Materials Science (miscellaneous) (Q2)
Physics and Astronomy (miscellaneous) (Q2)
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9
Atıf
5
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4
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