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A systematic comparative study of the efficient co-catalyst-free photocatalytic hydrogen evolution by transition metal oxide nanofibers

International Journal of Hydrogen Energy · Eylül 2018

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YÖKSİS Kayıtları
A systematic comparative study of the efficient co-catalyst-free photocatalytic hydrogen evolution by transition metal oxide nanofibers
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY · 2018 SCI
DOKTOR ÖĞRETİM ÜYESİ GİZEM YILDIZ →
A systematic comparative study of the efficient co-catalyst-free photocatalytic hydrogen evolution by transition metal oxide nanofibers
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY · 2018 SCI
DOÇENT EMRE ASLAN →
A systematic comparative study of the efficient co-catalyst-free photocatalytic hydrogen evolution by transition metal oxide nanofibers
International Journal of Hydrogen Energy · 2018 SCI-Expanded
PROFESÖR İMREN HATAY PATIR →
A systematic comparative study of the efficient co-catalyst-free photocatalytic hydrogen evolution by transition metal oxide nanofibers
International Journal of Hydrogen Energy · 1900 SCI-Expanded
PROFESÖR İMREN HATAY PATIR →

Makale Bilgileri

DergiInternational Journal of Hydrogen Energy
Yayın TarihiEylül 2018
Cilt / Sayfa43 · 17185-17194
Özet The efficiencies of a series of hydrogen evolving catalysts based on metal oxide nanofibers (NiO, Co3O4, Mn3O4) are investigated for the photocatalytic hydrogen evolution from water without using any co-catalyst under the visible light irradiation by using triethanolamine (TEOA) as an electron donor and Eosin-Y (EY) dye as a photosensitizer. It is found that the photocatalytic hydrogen evolution activities follow the order as: Mn3O4<Co3O4<NiO (196 μmolg−1h−1, 5552 μmolg−1h−1, 7757 μmolg−1h−1, respectively). Moreover, the catalytic behavior of these nanofibers on the hydrogen production has been also compared to bulk forms of NiO, Co3O4 and Mn3O4 by producing hydrogen 937 μmolg−1h−1, 901 μmolg−1h−1 and 135 μmolg−1h−1, respectively. The nanofiber structures demonstrated much higher photocatalytic activity than bulk forms due to the effect of the increased surface to volume ratio deduced from the fibrous character. The photocatalytic plausible pathway for the hydrogen production is also discussed.

Yazarlar (5)

1
Gizem Yanalak
2
Abdalaziz Aljabour
3
Emre Aslan
4
Faruk Ozel
ORCID: 0000-0002-3689-0469
5
Imren Hatay Patir
ORCID: 0000-0003-2937-6557

Anahtar Kelimeler

Co-catalyst free Hydrogen evolution Metal oxide Nanofibers

Kurumlar

Karamanoğlu Mehmetbey Üniversitesi
Karaman Turkey
Selçuk Üniversitesi
Selçuklu Turkey

Metrikler

31
Atıf
5
Yazar
4
Anahtar Kelime