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Ternary and quaternary thiospinel nanocrystals with adjustable compositions: effects of Band-Gaps and nanostructures on Visible-Light-Driven photocatalytic H<inf>2</inf> evolution

Materials Today Energy · Haziran 2020

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YÖKSİS Kayıtları
Ternary and quaternary thiospinel nanocrystals with adjustable compositions: effects of Band-Gaps and nanostructures on Visible-Light-Driven photocatalytic H2 evolution
Materials Today Energy · 2020 SCI-Expanded
DOKTOR ÖĞRETİM ÜYESİ GİZEM YILDIZ →
Ternary and quaternary thiospinel nanocrystals with adjustable compositions: effects of Band-Gaps and nanostructures on Visible-Light-Driven photocatalytic H-2 evolution
Materials Today Energy · 2020 SCI-Expanded
PROFESÖR İMREN HATAY PATIR →
Ternary and quaternary thiospinel nanocrystals with adjustable compositions: effects of Band-Gaps and nanostructures on Visible-Light-Driven photocatalytic H-2 evolution
Materials Today Energy · 2020 SCI-Expanded
DOÇENT EMRE ASLAN →

Makale Bilgileri

DergiMaterials Today Energy
Yayın TarihiHaziran 2020
Cilt / Sayfa16
Özet Ternary and quaternary structured thiospinel nanocrystals are important materials for energy applications based on their outstanding characteristics such as earth abundant components, non-toxic nature and simple production. In this study, CuNiCoS4, CuCo5S8 and CuCo2S4 nanocrystals have been successfully synthesized via hot injection-method with generalized synthesis conditions and detailed structural, optical and electrochemical characterizations were performed for the first time. The characterization results indicated that the nanocrystals were single phase, nearly stoichiometric composition and a mean size below 10 nm. Moreover, the synthesized nanocrystals have been used for the photocatalytic hydrogen evolution as a catalyst under visible light irradiation. In these reactions, CuNiCoS4 nanocrystals exhibited higher photocatalytic activity and stability than the others. CuNiCoS4 and CuCo5S8 catalyst have firstly been proven as valuable alternatives to CuCo2S4 structure and Platinum in hydrogen evolution reactions and are of particular interest due to lower costs, ease of fabrication and comparable evolution performance.

Yazarlar (6)

1
Adem Sarilmaz
ORCID: 0000-0003-1463-9764
2
Gizem Yanalak
3
Emre Aslan
4
H. Akyildiz
5
Imren Hatay Patir
ORCID: 0000-0003-2937-6557
6
Faruk Ozel
ORCID: 0000-0002-3689-0469

Anahtar Kelimeler

CuCo S 2 4 CuCo S 5 8 CuNiCoS 4 Hydrogen evolution Water splitting

Kurumlar

Karamanoğlu Mehmetbey Üniversitesi
Karaman Turkey
Konya Technical University
Konya Turkey
Selçuk Üniversitesi
Selçuklu Turkey

Metrikler

13
Atıf
6
Yazar
5
Anahtar Kelime