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Adsorption of Cu(II) onto silica gel-immobilized Schiff base derivative

Desalination · Aralık 2009

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YÖKSİS Kayıtları
Adsorption of Cu II onto silica gel immobilized Schiff base derivative
Desalination · 2009 SCI-Expanded 6 atıf
PROFESÖR İLKAY HİLAL GÜBBÜK →
Adsorption of Cu II onto silica gel immobilized Schiff base derivative
Desalination · 2009 SSCI
PROFESÖR HÜSEYİN KARA →

Makale Bilgileri

DergiDesalination
Yayın TarihiAralık 2009
Cilt / Sayfa249 · 1243-1248
Özet 4-chloroisonitroacetophenone 4-aminobenzylhydrazone (CAAH) chemically anchored on a silica gel surface, has been used for Cu(II) sorption from aqueous solution. The surface modification processes was performed after silanization of silica, then analyzed by elemental analysis, infrared spectroscopy, and thermogravimetry. The sorption behavior of copper(II) was evaluated by the use of batch and column methods. The influences of the concentration, temperature and pH for sorption on the immobilized silica gel with Schiff base were investigated. The obtained dynamic data were fitted to Freundlich, Langmuir and Dubinin-Raduskevich (D-R) isotherms. The mean sorption energy (E) of copper sorption onto silica gel was calculated from D-R isotherm indicating a chemical ion-exchange. The thermodynamic parameters such as Gibbs free energy change, enthalpy change and entropy change were calculated from the adsorption isotherms which were used to explain the mechanism of the adsorption. © 2009.

Yazarlar (4)

1
Ilkay Hilal Gubbuk
2
Ramazan Gup
3
Huseyin Kara
4
Mustafa Ersöz

Anahtar Kelimeler

Adsorption HPLC Immobilization Isotherm Silica gel

Kurumlar

Muğla Sıtkı Koçman Üniversitesi
Mugla Turkey
Selçuk Üniversitesi
Selçuklu Turkey

Metrikler

56
Atıf
4
Yazar
5
Anahtar Kelime