Scopus
YÖKSİS Eşleşti
Investigation of microwave assisted synthesis of Schiff Base derived Metal-Chelates by liquid invert sugar containing D-Glucose
Inorganic and Nano-Metal Chemistry · Ocak 2023
YÖKSİS Kayıtları
Investigation of microwave assisted synthesis of Schiff Base derived Metal-Chelates by liquid invert sugar containing D-Glucose
INORGANIC AND NANO-METAL CHEMISTRY · 2024 SCI-Expanded
PROFESÖR ZİYA ERDEM KOÇ →
Makale Bilgileri
DergiInorganic and Nano-Metal Chemistry
Yayın TarihiOcak 2023
Scopus ID2-s2.0-85152407422
Özet
The ethanol-soluble (6E,6'E)-6,6'-(1,2-phenylenebis(azan-1-yl-1-ylidene))dihexane-1,2,3,4,5-pentaol (LISPDA) and (E)-6-(2-hydroxyphenylimino)hexane-1,2,3,4,5-pentaol (LISAP) were investigated in this study. Condensation of 1,2-phenylenediamine and 2-aminophenol with 2,3,4,5,6-pentahydroxyhexanal (GL) in the presence of weak acid as a catalyst under mono-mode microwave heating yielded the glucose-Schiff base product. A one-pot microwave-assisted reaction in a short reaction time was required to complete the imine condensation reaction with 90% yield and no byproducts. The molecular structures of these were discovered to be in an extended conformation, with the aromatic moiety coplanar with that of the imine bond and the imine bond exhibiting trans-geometry. Schiff base metal complexes were successfully synthesized by combining 1,2-phenylenediamine and 2-aminophenol with D-glucose and Co(II), Ni(II), and Cu(II). Elemental analysis, magnetic susceptibility, thermal analysis, and electronic and infrared spectral studies were used to determine the structural assessment of ML2 complexes.
Yazarlar (6)
1
Ayse Ozer
2
Didem Elif Yasa
3
Dilara Hanim Sahin
4
Havva Turbayindir
5
E. Pehlivan
6
Ziya Erdem Koç
Anahtar Kelimeler
D-glucose
liquid invert sugar
microwave
Schiff bases
Sucrose
transition metal complexes
Kurumlar
Konya Technical University
Konya Turkey
Selçuk Üniversitesi
Selçuklu Turkey