SCI-Expanded
JCR Q1
Özgün Makale
Scopus
Novel fluorescent microcapsules based on sporopollenin for removal and detection of Cu (II) ions in aqueous solutions: Eco-friendly design, fully characterized, photophysical&physicochemical data
Microporous and Mesoporous Materials
2022
Cilt 330
Scopus Eşleşmesi Bulundu
41
Atıf
330
Cilt
Scopus Yazarları: Aysel Çimen, Hacer Sibel Karapınar, Ali Bilgiç, Ahmed Nuri Kursunlu
Özet
Sporopollenin is a natural substance found in plant walls and is highly resistant to external factors. In this paper, we designed an eco-friendly hybrid material, Sp-EDA-BODIPY, based on sporopollenin microcapsule and BODIPY to remove and detect metal ions. The fluorescent surface was fully characterized with various methods such as XRD, SEM, FT-IR, fluorescence spectroscopy. The fluorescent microcapsule sensor showed fluorometrically a remarkable quenching effect in the presence of Cu (II) ion, via the complexation mechanism that LOD it was calculated as 0.773 μM. As a result of the competing ion experiments, Sp-EDA-BODIPY also has a high selective for Cu (II) ion toward another the studied metal ions. Otherwise, we also calculated the adsorption capacities and the maximum isotherm parameters and from the Freundlich, Langmuir, and Dubinin-Radushkevich equations for the removal of Cu (II) with Sp-EDA-BODIPY fluorescent microcapsule. The maximum adsorption capacities of Cu (II) on Sp-EDA-BODIPY were calculated to be 28.65, 31.25, 34.02, and 37.74 mg/g at different temperatures (298, 308, 318, and 328 K), respectively. The adsorption experimental results were closer to Langmuir adsorption isotherm and pseudo-second-order models. Thermodynamic data showed that the adsorption process was endothermic, possible, and spontaneous.
Anahtar Kelimeler (Scopus)
Fluorescent
Microcapsule
Detection
Removal
Sporopollenin
Anahtar Kelimeler
Fluorescent
Microcapsule
Detection
Removal
Sporopollenin
Makale Bilgileri
Dergi
Microporous and Mesoporous Materials
ISSN
1387-1811
Yıl
2022
/ 1. ay
Cilt / Sayı
330
Makale Türü
Özgün Makale
Hakemlik
Hakemli
Endeks
SCI-Expanded
JCR Quartile
Q1
TEŞV Puanı
81,00
Yayın Dili
Türkçe
Kapsam
Uluslararası
Toplam Yazar
4 kişi
Erişim Türü
Elektronik
Erişim Linki
Makaleye Git
Alan
Fen Bilimleri ve Matematik Temel Alanı
Kimya
YÖKSİS Yazar Kaydı
Yazar Adı
BİLGİÇ ALİ, ÇİMEN AYSEL, KURŞUNLU AHMED NURİ, KARAPINAR HACER SİBEL
YÖKSİS ID
6446435
Hızlı Erişim
Metrikler
Scopus Atıf
41
JCR Quartile
Q1
TEŞV Puanı
81,00
Yazar Sayısı
4