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SCI-Expanded JCR Q1 Özgün Makale Scopus
Novel fluorescent microcapsules based on sporopollenin for removal and detection of Cu (II) ions in aqueous solutions: Eco-friendly design, fully characterized, photophysical&physicochemical data
Microporous and Mesoporous Materials 2022 Cilt 330
Scopus Eşleşmesi Bulundu
41
Atıf
330
Cilt
Scopus Yazarları: Aysel Çimen, Hacer Sibel Karapınar, Ali Bilgiç, Ahmed Nuri Kursunlu
Özet
Sporopollenin is a natural substance found in plant walls and is highly resistant to external factors. In this paper, we designed an eco-friendly hybrid material, Sp-EDA-BODIPY, based on sporopollenin microcapsule and BODIPY to remove and detect metal ions. The fluorescent surface was fully characterized with various methods such as XRD, SEM, FT-IR, fluorescence spectroscopy. The fluorescent microcapsule sensor showed fluorometrically a remarkable quenching effect in the presence of Cu (II) ion, via the complexation mechanism that LOD it was calculated as 0.773 μM. As a result of the competing ion experiments, Sp-EDA-BODIPY also has a high selective for Cu (II) ion toward another the studied metal ions. Otherwise, we also calculated the adsorption capacities and the maximum isotherm parameters and from the Freundlich, Langmuir, and Dubinin-Radushkevich equations for the removal of Cu (II) with Sp-EDA-BODIPY fluorescent microcapsule. The maximum adsorption capacities of Cu (II) on Sp-EDA-BODIPY were calculated to be 28.65, 31.25, 34.02, and 37.74 mg/g at different temperatures (298, 308, 318, and 328 K), respectively. The adsorption experimental results were closer to Langmuir adsorption isotherm and pseudo-second-order models. Thermodynamic data showed that the adsorption process was endothermic, possible, and spontaneous.
Anahtar Kelimeler (Scopus)
Fluorescent Microcapsule Detection Removal Sporopollenin

Anahtar Kelimeler

Fluorescent Microcapsule Detection Removal Sporopollenin

Makale Bilgileri

Dergi Microporous and Mesoporous Materials
ISSN 1387-1811
Yıl 2022 / 1. ay
Cilt / Sayı 330
Makale Türü Özgün Makale
Hakemlik Hakemli
Endeks SCI-Expanded
JCR Quartile Q1
TEŞV Puanı 81,00
Yayın Dili Türkçe
Kapsam Uluslararası
Toplam Yazar 4 kişi
Erişim Türü Elektronik
Erişim Linki Makaleye Git
Alan Fen Bilimleri ve Matematik Temel Alanı Kimya

YÖKSİS Yazar Kaydı

Yazar Adı BİLGİÇ ALİ, ÇİMEN AYSEL, KURŞUNLU AHMED NURİ, KARAPINAR HACER SİBEL
YÖKSİS ID 6446435

Metrikler

Scopus Atıf 41
JCR Quartile Q1
TEŞV Puanı 81,00
Yazar Sayısı 4