SCI-Expanded
JCR Q1
Özgün Makale
Scopus
Ternary nanocomposites of mesoporous graphitic carbon nitride/black phosphorus/gold nanoparticles (mpg-CN/BP-Au) for photocatalytic hydrogen evolution and electrochemical sensing of paracetamol
Applied Surface Science
2021
Cilt 557
Scopus Eşleşmesi Bulundu
35
Atıf
557
Cilt
Scopus Yazarları: Emre Aslan, Mustafa Ozmen, Salih Zeki Bas, Gizem Yanalak, Fatmanur Doganay, Zafer Eroğlu, Huseyin Kucukkececi, Önder Metin, Imren Hatay Patir
Özet
We report herein the fabrication of a novel ternary nanocomposite of mesoporous graphitic carbon nitride/black phosphorus-gold nanoparticles (mpg-CN/BP-Au) and its catalytic performance in the photocatalytic hydrogen evolution reaction (HER) and electrochemical detection of paracetamol. The photocatalytic hydrogen production rate of mpg-CN/BP-Au nanocomposite (1024 µmol g−1 for 8 h) is compared with mpg-CN, mpg-CN/BP and mpg-CN/Au in the presence of triethanolamine (TEOA) as a hole scavenger under the visible light. In addition to the photocatalytic HER application, as-prepared mpg-CN/BP-Au nanocomposite was deposited on modified glassy carbon electrode (mpg-CN/BP-Au/GCE) and for the first time tested for the detection of paracetamol (PA). Under the optimum conditions, linear range of paracetamol detection was found to be in the range of 0.3–120 µM with a detection limit of 0.0425 µM. mpg-CN/BP-Au/GCE provided higher electrocatalytic activity than pristine mpg-CN and all other tested binary nanocomposites. The enhanced photo- and electrochemical activity of mpg-CN/BP-Au/GCE are attributed to formation of heterojunction between BP and mpg-CN materials. Additionally, Au nanoparticles increase the rate of adsorption of mpg-CN/BP due to the excellent electrical properties and spillover effect. We believe that the presented design and catalysis of the ternary nanocomposite will pave a way in many photo- and electrochemical applications.
Anahtar Kelimeler (Scopus)
Black phosphorus
Electrochemical sensor
Graphitic carbon nitride
Paracetamol
Photocatalysts
Anahtar Kelimeler
Black phosphorus
Electrochemical sensor
Graphitic carbon nitride
Paracetamol
Photocatalysts
Makale Bilgileri
Dergi
Applied Surface Science
ISSN
0169-4332
Yıl
2021
/ 8. ay
Cilt / Sayı
557
Makale Türü
Özgün Makale
Hakemlik
Hakemli
Endeks
SCI-Expanded
JCR Quartile
Q1
TEŞV Puanı
2,00
Yayın Dili
Türkçe
Kapsam
Uluslararası
Toplam Yazar
9 kişi
Erişim Türü
Elektronik
Erişim Linki
Makaleye Git
Alan
Fen Bilimleri ve Matematik Temel Alanı
Kimya
Fiziksel Kimya
Elektrokimya
Nanoteknoloji
YÖKSİS Yazar Kaydı
Yazar Adı
YANALAK GİZEM, Doganay Fatmanur, Eroglu Zafer, Kucukkececi Huseyin, ASLAN EMRE, ÖZMEN MUSTAFA, BAŞ SALİH ZEKİ, METİN ÖNDER, HATAY PATIR İMREN
YÖKSİS ID
5521551
Hızlı Erişim
Metrikler
Scopus Atıf
35
JCR Quartile
Q1
TEŞV Puanı
2,00
Yazar Sayısı
9