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SCI-Expanded JCR Q2 Özgün Makale Scopus
Cyclic Oxidation Behavior and Protective Oxide Scale Formation in Stainless-Steel Alloys for High-Temperature Exhaust Valve Applications
Coatings 2025 Cilt 15
Scopus Eşleşmesi Bulundu
15
Cilt
🔓
Açık Erişim
Scopus Yazarları: Emin Salur, Gökhan Arici, Ahmed Degnah, S. Bilal Çetinkal, Halit Sübütay, İlyas Şavklıyıldız, Mehmet Şahin Ataş, Abdulaziz Kurdi, Abdulaziz AlHazaa
Özet
As internal combustion engine (ICE) systems are increasingly exposed to severe thermal and oxidative environments, the oxidation resistance and structural integrity of exhaust valve materials have become critical for maintaining long-term engine reliability and efficiency. This study presents a comparative evaluation of the cyclic oxidation behavior of two candidate valve steels, 1.4718 (ferritic stainless steel) and 1.4871 (austenitic stainless steel), under service-temperature conditions. The specimens were exposed to repeated oxidation at 550 °C, 650 °C and 750 °C for 25 cycles in ambient air. The surface and cross-sectional morphologies of the oxide layers were analyzed using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) to investigate oxide scale composition, thickness, and growth characteristics. The oxidation behavior of both alloys proceeded in two distinct stages: an initial phase marked by accelerated oxidation, followed by a slower, more stable growth period. The extent of oxidation intensified with increasing temperature. The 1.4718 alloy developed relatively porous but compositionally stable oxide layers consisting primarily of Fe- and Cr-based spinels such as FeCr<inf>2</inf>O<inf>4</inf> and Cr<inf>2</inf>SiO<inf>4</inf>. In contrast, the 1.4871 alloy formed a dense, adherent, dual-layered oxide scale composed of an outer Mn<inf>2</inf>O<inf>3</inf>-rich layer and an inner Cr<inf>2</inf>O<inf>3</inf>-rich layer, attributable to its high Mn and Cr content. The results underscore the critical influence of elemental composition, particularly Cr, Mn and Si, on oxide scale stability and spallation resistance, demonstrating the superior cyclic oxidation resistance of the 1.4871 alloy and its potential suitability for exhaust valve applications in thermally aggressive environments.
Anahtar Kelimeler (Scopus)
1.4718 microstructure oxidation 1.4871 SEM

Anahtar Kelimeler

1.4718 microstructure oxidation 1.4871 SEM

Makale Bilgileri

Dergi Coatings
ISSN 2079-6412
Yıl 2025 / 9. ay
Cilt / Sayı 15
Makale Türü Özgün Makale
Hakemlik Hakemli
Endeks SCI-Expanded
JCR Quartile Q2
TEŞV Puanı 16,00
Yayın Dili İngilizce
Kapsam Uluslararası
Toplam Yazar 9 kişi
Erişim Türü Basılı+Elektronik
Erişim Linki Makaleye Git
Alan Mühendislik Temel Alanı Malzeme ve Metalurji Mühendisliği

YÖKSİS Yazar Kaydı

Yazar Adı ÇETİNKAL SALİH BİLAL,ATAŞ MEHMET ŞAHİN,SALUR EMİN,ŞAVKLIYILDIZ İLYAS,SÜBÜTAY HALİT,ARICI GÖKHAN,Kurdi Abdulaziz,Degnah Ahmet,AlHazaa Abdulaziz
YÖKSİS ID 9230175

Metrikler

JCR Quartile Q2
TEŞV Puanı 16,00
Yazar Sayısı 9